系统地研究产业化甚高频等离子体增强化学气相沉积法制备p型a-SiO2:H薄膜的工艺,并将P型a-SiOx:H作为a-Si:H单结电池的窗口层,研究其对电池初始和稳定性能的影响。研究表明CO2与SiH4流量比(r(CO2/SiH4))、射频功率对a-SiOx:H薄膜的光电性能影响最大,r(CO2/SiH4)=1.5和功率=444W时制备的P型a-SiOx:H薄膜材料性能最优。相对于a-SiCx:H的p型窗口层,采用优化的p型a-SiOx:H薄膜作为窗口层的a-Si:H单结电池具有相同的初始发电功率,但具有更好的稳定性能,降低了光致衰减。电池的光致衰减率相对降低11.2%,功率输出的稳定性相对提升2%。
A series of p type a-SiOx : H single films were prepared by VHF PECVD on large size substrate, a-Si : H single junction solar cells with different p type a-SiOx : H window layer were also prepared and these cell' s initial and stable I-V characteristics were compared. The results showed that the p type a-SiOx :H film optical and electrical performance were changed with various r(CO2/SiH4)and RF power. Film with r(CO2/SiH4)=1.5 and RF power=444 W shows the best performance. Compared to a-Si: H single junction solar cell with p type a-SiCx: H, a-Si: H single junction solar cell with p type a-SiOx: H obtained the same initial power and better LID (Light Induced Degradation) performance. The LID ratio of a-Si: H single junction solar cell with p type a-SiOx :H is 11.2% lower and stable power is 2% higher than the cell with p type a-SiCx :H.