研究了La^3+,Sr^2+置换对Ca[(Mg1/3Nb2/3)0.6Ti0.4]O3陶瓷微观结构与微波介电性能的影响。研究结果表明:La^3+,Sr^2+置换改性Ca[(Mg1/3Nb2/3)0.6Ti0.4]O3系列陶瓷均形成了单一正交系的钙钛矿结构;随着置换量的增加,La^3+改性Ca[(Mg1/3Nb2/3)0.6Ti0.4]O3陶瓷的介电常数、介电损耗下降,同时谐振频率温度系数向正的方向移动,而Sr^2+改性陶瓷则表现出相反的规律,其主要原因在于La^3+,Sr^2+置换所引起Ca[(Mg1/3Nb2/3)0.6TiO4]O3陶瓷内部氧八面体结构变化上的差异。
The effect of La^3+ , Sr^2+ on the microstructure and microwave properties of CaO-MgO-Nb2O5-TiO2 system ceramics was investigated. The result shows that a single complex perovskite structure formed within investigated composition range in La^3+ , Sr2-doped CaO-MgO-Nb2O5-TiO2 system ceramics. With increasing of La^3+ , Sr^2+ content, the structure of La^3+, Sr2-doped CaO-MgO-Nb2O5-TiO2 system ceramic maintain orthorhombic type. It is found that La^3+ improves the microwave properties of CaO-MgO-Nb2O5-TiO2 ceramic, but Sr^2+ does not. The microwave properties of La^3+ , Sr2-doped CaO-MgO-Nb2O5-TiO2 system ceramics depend on the degree of octahedral distortion inside materials.