中文摘要：

偏苯三甲酸酐分别与4,4′-二氨基二苯甲烷、4,4′-二氨基二苯砜、4,4′-二氨基二苯醚,通过亚胺化反应,合成了3种含亚胺环结构的二元酸,在Lewis碱催化下通过酰化,得到了3种含亚胺环结构的二元芳酰氯.用FT-IR1、H-NMR1、3C-NMR等对3种芳酰氯进行了结构表征.结果表明,合成的目标产物具有预期结构,并有较高的产率.

英文摘要：

Three novel aromatic dicarboxylic acid chloride （DIDC） containing imido group were synthesized with high yields（90.5 % -95.3 % ） by acidylated the corresponding diimide-diacid （DIDA） in the presence of thionyl chloride and N,N′-dimethyl-formamide （DMF） as catalyst. DIDA were prepared from trimellitic anhydride with 4, 4′-diaminodiphenylmethane（ DDM ）, 4, 4′-diaminodiphenylsulfone （ DDS ） and 4, 4′-di -aminodiphenylether （ DDO ） respectively. DIDA and DIDC were obtained as designed and confirmed by FT-IR, 1^H-NMR and 13^C-NMR advanced analytic technology.