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An experimental study on the solubility of copper bichloride in water vapor
  • ISSN号:1001-6538
  • 期刊名称:科学通报(英文版)
  • 时间:0
  • 页码:395-400
  • 语言:中文
  • 分类:P592[天文地球—地球化学;天文地球—地质学] O614.121[理学—无机化学;理学—化学]
  • 作者机构:[1]State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
  • 相关基金:Supported jointly by the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCX3-SW-125), the National Natural Science Foundation of China (Grant Nos. 40503007 and 40373020) and the Western Light Program.The authors wish to express their special thanks to the editors and anonymous reviewers for their valuable comments and suggestions.
  • 相关项目:铜在水蒸气相中溶解及在气/液相之间分配机理的实验研究
中文摘要:

用溶解度方法, CuCl_2 inliquid-undersaturated 忍受 HCl 水蒸汽的溶解度在温度 of330 试验性地被调查—4.2 的 370 个鈩?a nd 压力—10 MPa。结果证明了水和能显著地提高铜溶解度,铜的集中断然与 P_(H_2O ) 被相关。在蒸汽阶段的铜的溶解度与在经常的温度增加 P_(H_2O ) 增加了。在水蒸汽作为含水的种类 CuCl_2 (H_2O )_n~( 气体) 搬运的 CuCl_2was。建筑群的 Theformation 被建议是下列反应的结果:CuCl_2~( 固体)+nH_2O ~( 气体)= CuCl_2 (H_2O )_n~( 气体) 水和数字 n 与增加温度稍微减少了。统计水和数字分别地在 330, 350 和 370 ℃是 4.0, 3.6 和 3.3。

英文摘要:

Using the solubility method, the solubility of CuCl2 in liquid-undersaturated HCl-bearing water vapor was investigated experimentally at temperatures of 330-370℃ and pressures of 4.2-10 MPa. The resuits have shown that hydration could significantly enhance copper solubility and the concentrations of copper were positively correlated with PH2O. The solubility of copper in vapor phase increased with increasing PH2O at the constant temperature. CuCl2 was transported as hydrated species CuCl2(H2O)n^gas in water vapor. The formation of complexes is proposed to be the result of the following reaction: CuCl=^solld + nH2O^gas = CuCl2 (H=O)n^gas The hydration number n decreased slightly with increasing temperature. Statistical hydration numbers are 4.0, 3.6 and 3.3 at 330, 350 and 370℃, respectively.

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