用溶解度方法, CuCl_2 inliquid-undersaturated 忍受 HCl 水蒸汽的溶解度在温度 of330 试验性地被调查—4.2 的 370 个鈩?a nd 压力—10 MPa。结果证明了水和能显著地提高铜溶解度,铜的集中断然与 P_(H_2O ) 被相关。在蒸汽阶段的铜的溶解度与在经常的温度增加 P_(H_2O ) 增加了。在水蒸汽作为含水的种类 CuCl_2 (H_2O )_n~( 气体) 搬运的 CuCl_2was。建筑群的 Theformation 被建议是下列反应的结果:CuCl_2~( 固体)+nH_2O ~( 气体)= CuCl_2 (H_2O )_n~( 气体) 水和数字 n 与增加温度稍微减少了。统计水和数字分别地在 330, 350 和 370 ℃是 4.0, 3.6 和 3.3。
Using the solubility method, the solubility of CuCl2 in liquid-undersaturated HCl-bearing water vapor was investigated experimentally at temperatures of 330-370℃ and pressures of 4.2-10 MPa. The resuits have shown that hydration could significantly enhance copper solubility and the concentrations of copper were positively correlated with PH2O. The solubility of copper in vapor phase increased with increasing PH2O at the constant temperature. CuCl2 was transported as hydrated species CuCl2(H2O)n^gas in water vapor. The formation of complexes is proposed to be the result of the following reaction: CuCl=^solld + nH2O^gas = CuCl2 (H=O)n^gas The hydration number n decreased slightly with increasing temperature. Statistical hydration numbers are 4.0, 3.6 and 3.3 at 330, 350 and 370℃, respectively.