中文摘要：

以高氯酸锌、1,2-丙二胺（1,2-pn）为原料在甲醇介质中反应,合成得到了新颖单核锌配合物[Zn（1,2-pn）3]（ClO4）2,用元素分析、IR、1HNMR和热重分析等手段对该化合物的结构进行了表征,并用单晶X-射线衍射法测得其晶体结构为单斜晶系,空间点群为C2/c,晶体学参数为：a=2.971 4（11）nm,b=0.978 0（4）nm,c=1.780 3（5）nm,α=90.00°,β=122.90（2）°,γ=90.00°,V=4.344（3）nm3,Dc=1.488 g/cm3,Z=8,F（000）=2 032,μ=1.421 mm-1。

英文摘要：

A novel mononuclear complex [Zn（ 1,2-pn）3 ] （ ClO4）2 was synthesized based on the reaction of zinc perchlorate bexahydrate with propune-1,2-diamine in methanol medium. Its structure was characterized by elemental analysis, IR spectrometry,1HNMR and thermal analysis. The crystal structure of the title compound was also determined by X：ray single crystal diffractometry. The crystal belonged to a monoclinic system with space group C2/c, and crystallographic data of the compound were： a=2.971 4（11）nm,b=0.978 0（4）nm,c=1.780 3（5）nm,α=90.00°,β=122.90（2）°,γ=90.00°,V=4.344（3）nm3,Dc=1.488 g/cm3,Z=8,F（000）=2 032,μ=1.421 mm-1.