对竹子碱木素进行了催化湿空气氧化降解。结果表明,竹子碱木素催化湿空气氧化的主要降解产物为3种芳香醛,含量从高到低依次为香草醛、对羟基苯甲醛和丁香醛。芳香醛浓度随降解时间的增加先升高后降低;催化剂的使用对芳香醛浓度有显著的影响,但不改变3种芳香醛的含量相对大小顺序;催化剂能较大地提高芳香醛的最高浓度,且能明显缩短芳香醛浓度达到极大值的时间;与无催化剂或蒽醌(AQ)作为催化剂相比,CuSO4/FeCl3作为催化剂时,能使芳香醛的浓度提高1倍以上,香草醛、对羟基苯甲醛、丁香醛的最高浓度分别为1.34、1.07、0.59 g/L,总芳香醛的最高浓度为2.87 g/L。
In this paper,bamboo alkaline lignin was degraded by catalytic wet air oxidation(CWAO).The results showed that three aromatic aldehydes were the main products,and their concentrations from high to low were as follows: vanillin,p-hydroxy benzaldehyde and syringaldehyde,which was considered as a feature of bamboo alkaline lignin;The concentrations of aromatic aldehydes increased at first and then decreased when the reaction time increased;Catalysts had a significant effect on the concentrations of aromatic aldehydes,but did not change the relative content of them;Using CuSO4/FeCl3 as catalysts,the concentrations of aromatic aldehydes were doubled comparing to no catalyst or using AQ as catalyst,and the concentrations of vanillin,p-hydroxy benzaldehyde and syringaldehyde were 1.34、1.07、0.59 g/L respectively while the total concentration of aromatic aldehydes was 2.87 g/L.