采用平衡合金法,利用X射线衍射、扫描电镜及能谱分析,确定Mg-Zn-Al三元系富镁角300°Cα-Mg相平衡关系和相组成。结果表明:在富镁角存在3个三相区:α-Mg+Mg17Al12(γ)+Al5Mg11Zn4(φ),α-Mg+Mg32(Al,Zn)49(τ)+Al5Mg11Zn4(φ)和α-Mg+MgZn+Mg32(Al,Zn)49(τ)。与α-Mg相平衡的金属间化合物都具有很大的成分范围,并非呈线性。同时Zn和Al都能够溶解在α-Mg固溶体中,使金属间化合物达到相平衡。
The phase equilibria and compositions in Mg-rich comer at 300℃ were determined in the Mg-Zn-A1 ternary system through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). The results show that there exist three three-phase regions consisted of a-Mg+Mg17A112(7)+A15Mg11Zn4(φ), a-Mg+Mga2(Al, Zn)49(r)+A15MgllZn4(φ) and a-Mg+MgZn+Mg32(A1, Zn)49(r), respectively. The intermetallic compounds in equilibrium with a-Mg phase all have large composition ranges, not appear to be linear. At the same time, both zinc and aluminum are soluble in the a-Mg solid solution, with which the compounds are in equilibrium.