系统讨论了绿潮浒苔的独特结构和功能特性,旨在制备纳米纤丝化的海藻纤维素和高比表面积的气凝胶材料,并为浒苔的高价值应用提供新的思路。将绿潮肇事种浒苔化学纯化脱去多糖、蛋白、脂肪后。用圆盘胶磨(20000r/min,20min)进行纳米纤丝化。制备出均一直径(大约40nm)和高长径比的Ic纳米纤丝化纤维素。经由叔丁醇置换和冷冻干燥后可以制备出高比表面积(277cm2/g)、密度为23mg/cm3的柔性纳米纤丝化纤维素气凝胶。所有这些结果通过扫描电镜(SEM)、红外光谱仪(FTIR)、X射线衍射仪(XRD)进行分析。在此基础上,采用机械法直接用胶体磨将浒苔原料进行纳米纤丝化,冷冻干燥后制备出全组分的浒苔泡沫材料。
This paper discusses the special structure and properties of algal cellulose of Ulva prolifera from green tide for preparing nanofibrillated cellulose (NFC) and aerogels with a high specific surface area. Valuable applications of NFC are reviewed for developing novel applications of Ulva prolifera. NFC was prepared using a simple grinding treatment (20000 r/min, 20 min) after the removal of polysaccharide, ester acid, protein and salt. The obtained cellulose I, NFC had a uniform width of approximately 40 nm and a high aspect ratio. Grinding is an effective way to convert raw cellulose to nanofibrils. Furthermore, we also prepared flexible algal cellulose aerogel with a low density (23 mg/cm3) and a high specific surface area (277 cm2/g) after t-BuOH freeze-drying. It is also revealed that t-BuOH freeze-drying is an efficient way to assemble ID NFC to meso-porous materials. All these results were confirmed by SEM, FTIR spectra, and X-ray diffraction profiles. On the basis of that, Ulva prolifera was nanofabrillated without any chemical purification by direct grinding, and algal foam was prepared with freeze-drying to fully use algae from green tide.