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己二酮糖硝基甲烷加合产物的结构确定
  • ISSN号：1000-4556
  • 期刊名称：波谱学杂志
  • 时间：2011
  • 页码：272-277
  • 分类：O657.31[理学—分析化学;理学—化学]
  • 作者机构：[1]中国科学院干旱区植物资源化学重点实验室,中国科学院新疆理化技术研究所,新疆乌鲁木齐830011, [2]新疆大学理化测试中心,新疆乌鲁木齐830046, [3]新疆大学化学化工学院,新疆乌鲁木齐830046, [4]中国科学院研究生院,北京100049
  • 相关基金：国家自然科学基金杰出青年科学基金资助项目（30925045）; 中国科学院、国家外国专家局创新团队国际合作伙伴计划项目联合资助
  • 相关项目：民族药学
作者： 贺耀武|孙万赋|曹玲华|周树宝|阿吉艾克拜尔·艾萨|
关键词： 核磁共振(NMR), 归属, 己二酮糖, 加合物, NMR, assignment, diketohexose, adduct
中文摘要：

立体选择性地合成了1,2：4,5-二-O-异亚丙基-3-C-硝基甲基-β-D-核-己-2-吡喃酮糖,确证了其绝对构型.并用gCOSY、gHSQC、gHMBC、ROESY等2D NMR技术对它的1H和13C NMR谱峰进行了全归属.

英文摘要：

1,2∶4,5-di-O-isopropylidene-3-C-nitromethyl-β-D-ribo-hex-2-ulo pyranose was synthesized with high stereoselectivity.Its absolute configuration was confirmed.The 1H and 13C NMR signals of the compound were assigned using 1D and 2D techniques,including 1H NMR,13C NMR,gCOSY,gHSQC,gHMBC and ROESY.

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期刊信息
  • 《波谱学杂志》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国科学院武汉物理与数学研究所 中国物理学会波谱学专业委员会
  • 主编：刘买利
  • 地址：湖北省武汉市武昌小洪山西区30号
  • 邮编：430071
  • 邮箱：magres@wipm.ac.cn
  • 电话：027-87198791
  • 国际标准刊号：ISSN：1000-4556
  • 国内统一刊号：ISSN：42-1180/O4
  • 邮发代号:38-313
  • 获奖情况:
  • 1992 年获国家科委、中宣部、新闻出版署首届优秀...,获中国科1996年获中国科学院优秀期刊三等奖,1999年获第三届湖北省优秀期刊奖 ，并被列为湖北...,2001年获第四届湖北省优秀期刊奖,2006年获第五届湖北省优秀期刊奖,2008年获第六届湖北省优秀期刊奖,2010年获第七届湖北省优秀期刊奖---湖北省专业技...,2013年获第八届湖北省优秀期刊奖
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  • 被引量:2740