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Dissolution behavior of calcium-magnesium-silicate glass fiber
  • ISSN号:1005-9784
  • 期刊名称:Journal of Central South University of Technology
  • 时间:2011.12.12
  • 页码:1833-1837
  • 分类:TQ171.777[化学工程—玻璃工业;化学工程—硅酸盐工业] TQ127.2[化学工程—无机化工]
  • 作者机构:[1]The Key State Laboratory Breeding Base of Refractories and Ceramics, Wuhan University of Science and Technology
  • 相关基金:Funded by the National High Technology Research and Development Program ("863" Program) of China (No.2009AA032503), the National Natural Science Fotuxiafion of China (Nos.50872098, 51004080), and the Open Fund of the Key Slate Labomtory Breeding Base of Refiactofies and Ceramics (Wuhan University of Science and Technology (No.G201004)
  • 相关项目:MgO-SiO2熔体分相与陶瓷纤维粉化机制研究
中文摘要:

Structure, crystallization and dissolution properties of CaO-MgO-SiO2 inorganic glass fiber in the presence of additives (Al2O3, Y2O3) were investigated by DTA, XRD, FTIR and ICP-AES techniques. The results show that with the addition of Al2O3 and Y2O3, the glass network structure is strengthened and the precipitation of crystals is inhibited for heat-treated fibers. Compared with Y2O3 doped fibers, Al2O3 presents more significant effects on the enhancement of silica network and the inhibition of crystallization in fibers. As for dissolution properties in physiological fluids, though the weight losses, changes of pH values and leached ions concentration lower slightly with the addition of Al2O3 and Y2O3 for the intensified network structure, and fibers still present high dissolution rates.

英文摘要:

Abstract: Structure, crystallization and dissolution properties of CaO-MgO-SiO2 inorganic glass fiber in the presence of additives (A12O3, Y2O3) were investigated by DTA, XRD, FTIR and ICP-AES techniques. The results show that with the addition ofAl2O3 and Y2O3, the glass network structure is strengthened and the precipitation of crystals is inhibited for heat-treated fibers. Compared with Y2O3 doped fibers, AI2O3 presents more significant effects on the enhancement of silica network and the inhibition of crystallization in fibers. As for dissolution properties in physiological fluids, though the weight losses, changes of pH values and leached ions concentration lower slightly with the addition ofA1203 and Y203 for the intensified network structure, and fibers still present high dissolution rates.

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