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288K时四元体系Na~+,K~+//Cl~-,B_4O_7~(2-)-H_2O相平衡研究
  • ISSN号:1673-6850
  • 期刊名称:盐业与化工
  • 时间:0
  • 页码:8-11
  • 分类:O642.42[理学—物理化学;理学—化学]
  • 作者机构:[1]成都理工大学材料与化学化工学院,四川成都610059, [2]矿产资源化学四川省高校重点实验室,四川成都610059
  • 相关基金:国家自然科学基金(No.40973047)、四川省杰出青年学科带头人培养资助计划(No.08ZQ026-017)和教育部新世纪优秀人才资助计划(No.NCET-07-0125)联合资助项目
  • 相关项目:川西盆地富硼钾溴地下卤水高温相平衡与相图研究
中文摘要:

采用等温溶解平衡法测定了三元体系KCl一KBr—H2O 323K时的相平衡数据,测定了平衡液相的溶解度和密度,依据湿渣法和x射线衍射相结合的方法对平衡固相组成做了分析。根据实验结果绘制了该三元体系在323K时的相图,研究表明:该三元体系相图属于完全互溶的固体溶液型相图,在323K的溶解度等温图中有1个固溶体结晶区K(Cl,Br),1条单变量曲线。还简要讨论了密度变化规律。同时和翁延博等人对该体系做的298K,313K,333K时的相平衡研究做了对比。

英文摘要:

Solubilities in the ternary system KCl - KBr - H2O at 323 K was investigated by i- sothermal equilibrium method. The saturated solution density was measured. The equilibrium solid phase was also determined by analyzed wet residue an X - ray spectroscopy. Based on the experimental data,the phase diagram of the ternary system at 323 K was obtained, which comprises one univariant curve and one stationary phase in crystallization filed of K( Cl, Br). The ternary system is a solid solution. The density rules were discussed briefly and the phase diagram of the ternary system at 323 K was compared with the phase diagram of the ternary system at 298K, 313K, 333 K.

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