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Characterization and Photocatalytic Activity of Mixed Nanocrystalline TiO2 Powders Prepared by Xerogel-Hydrothermal Method in Different Acid Solutions*
  • ISSN号:1006-4982
  • 期刊名称:《天津大学学报:英文版》
  • 时间:0
  • 分类:G4[文化科学—教育学;文化科学—教育技术学]
  • 作者机构:[1]School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China, [2]School of Science, Tianjin Chengjian University, Tianjin 300384, China, [3]School of Science, Tibet University, Tibet 850000, China
  • 相关基金:Supported by the National Basic Research Program of China (“973” Program, No. 2014CB239300, No. 2012CB720100) and National NaturalScience Foundation of China (No. 21406164, No. 21466035).
中文摘要:

TiO2 nanoparticles(NPs)were prepared via the hydrothermal route of TiO2 xerogel in nitric acid, hydrochloric acid and acetic acid. The physico-chemical properties of the powders were characterized by X-ray diffraction(XRD)and N2 adsorption desorption techniques. The effects of the different acids on the structure(crystal phase)and texture(primary particle size and porosity)of the TiO2 powders were explored. Results indicated that acetic acid facilitated the formation and stability of pure anatase phase. On the other hand, nitric acid and hydrochloric acid led to the transformation from anatase to rutile. The catalyst synthesized via the hydrothermal route of TiO2 xerogel in the low concentration hydrochloric acid solution(Ti-HCl-0.15)had the highest photocatalytic activity than the catalysts obtained in the other two acid solutions. The effects of the different acids were discussed in terms of acid strength, chelating effect and the thermal stability of the adsorbed acidic anions.

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期刊信息
  • 《天津大学学报:英文版》
  • 主管单位:中华人民共和国教育部
  • 主办单位:天津大学
  • 主编:龚克
  • 地址:天津市南开区卫津路92号天津大学第19教学桉东配楼
  • 邮编:300072
  • 邮箱:trans@tju.edu.cn
  • 电话:022-27400281
  • 国际标准刊号:ISSN:1006-4982
  • 国内统一刊号:ISSN:12-1248/T
  • 邮发代号:6-128
  • 获奖情况:
  • 天津市一级期刊,被国内外十余家检索机构收录
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,英国英国皇家化学学会文摘
  • 被引量:153