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Investigation of Microstructures and Anti-corrosion Properties of Aluminium-Zinc Alloys
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:O614.31[理学—无机化学;理学—化学] O614.33[理学—无机化学;理学—化学]
  • 作者机构:[1]Institute of Theoretical Chemistry, Shandong University, Jinan, Shandong 250100, China, [2]Department of Chemistry, National Sun Yat-sen University, Kaohsiung, Taiwan 80424, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (Nos. 20133020 and 20373033).
中文摘要:

电气化学的实验被执行测试铝锌的腐蚀率热剧降的涂层。5.3% 铝锌合金(重量比率) 有优异耐蚀性质,这被显示出。坚定的微观结构显示了由纳米组成的非结晶的结构系统的大小的粒子。分析显示了 5.3% 铝锌系统的吉布斯精力的大否定变化。分子的动力学模拟证明 5.3% 铝锌系统从另外的系统有很不同的行为。这个特别系统的阶段转变从模拟被观察。转变温度在 400 K 附近被决定。模拟显示 5.3% 铝锌系统在从 300 ~ 900 K 的温度范围上是非结晶的,支持从铝锌合金的非结晶的固体有的实验的推理特殊耐蚀特性。

英文摘要:

Electro-chemical experiment was carded out to test the corrosion rates of aluminium-zinc hot-dip coating. It is shown that 5.3% aluminium-zinc alloy (weight ratio) has superior anti-corrosion property. The determined microstructure has displayed amorphous structure composed of nanometer sized particle of the system. The analysis indicated large negative change of Gibbs energy of 5.3% aluminium-zinc system. Molecular dynamics simulation showed that 5.3% aluminium-zinc system has very different behavior from other systems. A phase transition of this particular system was observed from simulation. The transition temperature was determined around 400 K. The simulation indicated that 5.3% aluminium-zinc system is amorphous over temperature range from 300 to 900 K, supporting the inference from experiments that amorphous solid of aluminium-zinc alloy has special anti-corrosion character.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175