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多流体多次注射成型HDPE制品的结晶形态
  • ISSN号:1000-3304
  • 期刊名称:Acta Polymerica Sinica
  • 时间:2011.3.20
  • 页码:235-239
  • 分类:TQ336.9[化学工程—橡胶工业]
  • 作者机构:[1]四川大学高分子科学与工程学院,成都610065, [2]高分子材料工程国家重点实验室,成都610065
  • 相关基金:国家自然科学基金(基金号20734005)资助项目
  • 相关项目:多流体多次注入注射成型的理论基础及其制品的形态结构
中文摘要:

通过自主设计的多流体多次注射成型装置研究二次剪切应力场和复杂温度场对高密度聚乙烯晶体形态发展的影响.用偏光显微镜(PLM)和扫描电子显微镜(SEM)分析了多流体多次注射成型(multi—fluidmulti—injection molding,MFMIM)和传统注射成型(conventional injection molding,CIM)高密度聚乙烯(HDPE)制品的结晶形态,发现CIM试样小论是皮层还是芯层主要形成的是普通球晶,而在MFMIM中,由于皮层熔体受到二次强剪切应力作用,形成了环带球品和柱品的特殊结构,在形态分析的基础上,初步探讨了聚合物多流体多次注射成型制品结晶形态的形成机理.

英文摘要:

In order to explore the coupling effects of second shear flow and temperature fields on the formationas well as the evolution of crystal morphologies of high-density polyethylene (HDPE) , the crystal morphologies of the parts obtained by multi-fluid multi-injection molding (MFMIM) were investigated. The main feature of MFMIM is that the polymer melts in two different injection units are injected sequentially into the cavity to form an encapsulated sandwich-structure product. Polarizing light microscopy (PLM) results showed that some peculiar microstructures (e. g. cylindritic structures and ring-banded spherulites) were generated in the skin layer of the MFMIM parts. With the aid of scanning electronic microscopy (SEM) , a detailed description of cylindritic structure was obtained, which showed that the cylindritic structure consisted of some ring-banded spherulites. For comparison, the crystalline morphology of the sample molded by conventional injection molding (CIM) was also investigated. Different from the MFMIM parts, there were not observed any ring-banded spherulites or cylindritic structures in CIM parts except the common spherulites. And there was not a significant skin-core structure formed due to the higher temperature of the mold. Based on the comparison between the experimental results of the MFMIM parts and those of the CIM counterparts, it was concluded that the main reasons for ring-banded spherulites and cylindritic structures arising in the skin layer of MFMIM parts were the shearing and the complex thermo-mechanical fields provided by the secondary melt penetration process. Therefore, on the basis of the previous results, the mechanisms of ring-banded spherulites and cylindritic structures formation were discussed.

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期刊信息
  • 《高分子学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院化学研究所
  • 主编:张希
  • 地址:北京市海淀区中关村北一街2号
  • 邮编:100190
  • 邮箱:gfzxb@iccas.ac.cn
  • 电话:010-62588927
  • 国际标准刊号:ISSN:1000-3304
  • 国内统一刊号:ISSN:11-1857/O6
  • 邮发代号:2-498
  • 获奖情况:
  • 国家优秀期刊二等奖,中科院优秀期刊二等奖,中国科协优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19174