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橡胶阻尼减震材料的研究进展
  • ISSN号:1005-4030
  • 期刊名称:特种橡胶制品
  • 时间:2012.12.15
  • 页码:68-73+77
  • 分类:TQ325.14[化学工程—合成树脂塑料工业]
  • 作者机构:[1]华南理工大学材料科学与工程学院,广州510640
  • 相关基金:国家自然科学基金项目(51103048),广东省科技计划项目(20108010900013),华南理工大学高校基本科研业务费项目(2011ZM0128)
  • 相关项目:具有变温持续自修复性的硅橡胶自修复材料的制备、表征及其自修复机理研究
中文摘要:

通过机械剪切破碎法制备再生硅橡胶,并将其掺入硅橡胶中制备再生硅橡胶/硅橡胶共混物。研究了再生硅橡胶的含量、硫化剂DBPMH和沉淀白炭黑用量对共混物硫化特性和力学性能的影响,采用FTIR、DMA和SEM分析对共混物和硅橡胶进行表征。结果表明,随着共混物中再生硅橡胶含量的增加,共混物的硫化速度变慢,力学性能降低,当再生硅橡胶含量为46.9%时,共混物的综合力学性能较好。当硫化剂DBPMH用量为0.5份,且沉淀白炭黑用量为15份时,共混物具有良好的力学性能。FTIR分析表明,机械剪切破碎法没有引起再生硅橡胶化学性质的变化。DMA分析表明,共混物的玻璃化转变温度和硅橡胶接近,但tan6峰值下降。SEM分析表明,共混物的填料分散均匀性介于硅橡胶和再生胶之间。

英文摘要:

Recycled silicone rubber was prepared by mechanical shearing, which was added into MVQ rubber to prepare recycled silicone rubber/MVQ blends. The effect of recycled silicone rubber content, curing agent DBPMH and the precipitated silica content on the curing behavior and mechanical properties of the blends had been investigated. The blends and MVQ rubber were characterized by FTIR, DMA and SE analysis. The results showed that the curing speed of the blends becomes slower and the mechanical properties of the blends decrease with the increasing of recycled silicone rubber content. When recycled silicone rubber content is 46.9%, DBPMH content was 0.5 phr, and precipitated silica content is 15 phr, the blends show better mechanical properties. FTIR analysis showed that the chemical character of recycled silicone rubber doesn't cause any change by mechanical shearing. DMA analysis showed that the glass transition temperature of the blends and MVQ rubber is similar, but tan 5 peak of the blends declines. SEM analysis showed that filler dispersion of the blends is between the MVQ rubber and recycled silicone rubber.

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期刊信息
  • 《特种橡胶制品》
  • 主管单位:西北橡胶塑料研究设计院
  • 主办单位:西北橡胶塑料研究设计院
  • 主编:伍兆敏
  • 地址:咸阳市12号信箱
  • 邮编:712023
  • 邮箱:xinxi@fastrubber.com
  • 电话:029-33621370 33623217
  • 国际标准刊号:ISSN:1005-4030
  • 国内统一刊号:ISSN:61-1141/TQ
  • 邮发代号:52-42
  • 获奖情况:
  • 陕西省优秀科技期刊二等奖
  • 国内外数据库收录:
  • 被引量:4549