抓的铝上的镁免职溶解的电气化学的行为在 Grignard reagent/tetrahydrofuran ( THF )阻止答案( 1 摩尔 L1 EtMgBr/THF ),它被认为是可充电的镁电池的潜在的电解质,被使用象周期的 voltammetry ( CV )那样的各种各样的方法学习,扫描电子显微镜学( SEM ),X光检查衍射( XRD )和费用分泌物(免职溶解)测试。获得的镁扔的在场的结果不展出树突的形态学, Mg-Al 合金没在铝陪衬的表面上被发现。镁在 1 个摩尔 L1 EtMgBr/THF 解决方案在底层有的铝上扔了优秀电气化学的周期的性能。铝能为可充电的镁电池被用作否定当前的收集者的候选人材料。
The electrochemical behavior of magnesium deposition-dissolution on scratched aluminum foils in Grignard reagent/tetrahydrofuran (THF) solutions (1 mol L-1 EtMgBr/THF), which is regarded as a potential electrolyte of rechargeable magnesium batteries, was studied by using various methods such as cyclic voltammetry (CV), scanning electron microscopy (SEM), X-ray diffraction (XRD) and charge-discharge (deposition-dissolution) tests. The results present that the obtained magnesium deposits do not exhibit the morphology of dendrite and the Mg-Al alloy is not found on the surface of aluminum foils. The magnesium deposited on the aluminum substrates have excellent electrochemical cyclic performance in 1 mol L-1 EtMgBr/THF solution. The aluminum can be used as a candidate material of the negative current collector for rechargeable magnesium batteries.