中文摘要：

采用固相反应法合成了Bi2V0．9Cu0．1-xSnxO5．5-δ（0≤x≤0．75）系列化合物．X-ray粉末衍射分析表明所制样品均是四方1相．实验研究表明：Sn的掺入未能进一步改善体系的电学性质，但掺Sn有利于优化材料的微结构及材料力学性能的提高；氧渗透测量数据分析得到Bi2V0.9Cu0.05Sn0．05O5．5-δ陶瓷致密膜中氧的渗透输运过程主要是由表面氧交换控制的．

英文摘要：

The samples of Bi2V0.9Cu0.1-xSnxO5.5-δ （0≤ x ≤0.75） were prepared by solid-state reaction. Room temperature powder X-ray diffraction （XRD） indicates that the synthesized compounds present the tetragonal γ-phase structure. The measurement results show that doped-Sn benefits to the control of microstructure of the sample and favor its mechanic property though it doesn＇t further improve the electrical conductivity of the system. The oxygen permeation measurement result indicates oxygen transport in Bi2V0.9Cu0.1-xSnxO5.5-δ system is controlled mainly by the process of surface oxygen exchange.