石墨烯由于其特殊的单原子层结构决定了其具有丰富而新奇的物理化学性质.在发现后的短短十年问,已在物理学、化学、材料科学与工程等领域产生了重要的影响,成为备受瞩目的国际研究前沿和热点.在石墨烯的研究和应用中,最重要的问题就是如何实现其可控制备,组装及功能化应用.近年来,包括本课题组在内的国内外很多研究人员一直在积极探索石墨烯及其功能复合物的制备及应用新途径,其中石墨烯与导电高分子聚吡咯(PPy)的复合是研究的重要内容之一,并且取得了一系列有价值的研究成果.本文对石墨烯/PPy复合结构的可控制备进行了系统的归纳与总结,也讨论了其在催化、驱动器、超级电容器和传感器等电化学应用领域的最新进展,并对相关领域的发展趋势做了展望.
Due to its special monolayer structure,graphene has interesting physical and chemical properties. Over the past ten years, graphene studies have has produced great effects on physics, chemistry, and material science and engineering, and have become one of the high-profile international frontiers and research focuses. The controllable preparation, assembly and functional applications of graphenes are essential for graphene studies. In recent years, researchers are constantly exploring the new ways for preparation and application of graphenes and their functional composites. Among them, the composite of graphene and conductive polymer polypyrrole (PPy) has attracted much attention in particular, and a series of valuable insight into the new graphene/polymer composites has been achieved. In this report,the recent important advances in controllable synthesis of graphene/PPy composites are summarized and some of the new developments in the field of electrochemical applications, including catalysis, actuator, supercapacitors, sensors, and so on, are discussed.