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Facile production of ultrathin graphitic carbon nitride nanoplatelets for efficient visible-light water splitting
  • ISSN号:1000-372X
  • 期刊名称:《应用激光》
  • 时间:0
  • 分类:TQ163[化学工程—高温制品工业] TN248.4[电子电信—物理电子学]
  • 作者机构:[1]Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China
  • 相关基金:This project is sponsored by NSFC (Nos. 21325415, 21174019, 21301018, 51161120361), National Basic Research Program of China (2011CB013000), Basic Research Foundation of Beijing Institute of Technology (20121942008), Fok Ying Tong Education Foundation (No. 131043), the 111 Project B07012, Beijing Natural Science Foundation (2152028) and the Beijing Key Laboratory for Chemical Power Source and Green Catalysis under the contract no. 2013CX02031.
中文摘要:

Ultrathin graphitic 碳氮化物 nanoplatelets (UGCNP ) 被一种灵巧的方式经由一条有效、 eco 友好的球 milling 途径综合。获得的 UGCNP 在厚度是在尺寸和 0.350.7 nm 的 26 nm,与在体积 graphitic 碳氮化物的上的改进特定的表面区域。光化学的实验证明 UGCNP 在切开的可见光的水里是高度活跃的,与 1,365 摩尔的氢进化率 ??  ? 洠条敮楳瑯敨浲吗?

英文摘要:

Ultrathin graphitic carbon nitride nanoplatelets (UGCNPs) are synthesized by a facile manner via an efficient and eco-friendly ball milling approach. The obtained UGCNPs are 2-6 nm in size and 0.35-0.7 nm in thickness, with improved specific surface area over that of bulk graphitic carbon nitride. Photochemical experiments show that the UGCNPs are highly active in visible-light water splitting, with a hydrogen evolution rate of 1,365 μmol·h^-1·g^-1, which is 13.7-fold greater than that of their bulk counterparts. The notable improvement in the hydrogen evolution rate observed with UGCNPs under visible light is due to the synergistic effects derived from the increased specific surface area, reduced thickness, and a negative shift in the conduction band concomitant with the exfoliation of bulk graphitic carbon nitride into UGCNPs. In addition to metal- free visible-light-driven photocatalytic hydrogen production, the UGCNPs find attractive applications in biomedical imaging and optoelectronics because of their superior luminescence characteristics.

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期刊信息
  • 《应用激光》
  • 北大核心期刊(2011版)
  • 主管单位:
  • 主办单位:上海市激光技术研究所
  • 主编:王之江
  • 地址:上海市宜山路770号
  • 邮编:200233
  • 邮箱:yyjg@laser.net.cn
  • 电话:021-64700560-2107 64516313
  • 国际标准刊号:ISSN:1000-372X
  • 国内统一刊号:ISSN:31-1375/T
  • 邮发代号:4-376
  • 获奖情况:
  • 1996年上海市第二届优秀期刊评比二等奖
  • 国内外数据库收录:
  • 荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:5768