Ultrathin graphitic 碳氮化物 nanoplatelets (UGCNP ) 被一种灵巧的方式经由一条有效、 eco 友好的球 milling 途径综合。获得的 UGCNP 在厚度是在尺寸和 0.350.7 nm 的 26 nm,与在体积 graphitic 碳氮化物的上的改进特定的表面区域。光化学的实验证明 UGCNP 在切开的可见光的水里是高度活跃的,与 1,365 摩尔的氢进化率 ?? ? 洠条敮楳瑯敨浲吗?
Ultrathin graphitic carbon nitride nanoplatelets (UGCNPs) are synthesized by a facile manner via an efficient and eco-friendly ball milling approach. The obtained UGCNPs are 2-6 nm in size and 0.35-0.7 nm in thickness, with improved specific surface area over that of bulk graphitic carbon nitride. Photochemical experiments show that the UGCNPs are highly active in visible-light water splitting, with a hydrogen evolution rate of 1,365 μmol·h^-1·g^-1, which is 13.7-fold greater than that of their bulk counterparts. The notable improvement in the hydrogen evolution rate observed with UGCNPs under visible light is due to the synergistic effects derived from the increased specific surface area, reduced thickness, and a negative shift in the conduction band concomitant with the exfoliation of bulk graphitic carbon nitride into UGCNPs. In addition to metal- free visible-light-driven photocatalytic hydrogen production, the UGCNPs find attractive applications in biomedical imaging and optoelectronics because of their superior luminescence characteristics.