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Surface Functionalization of Microporous Polypropylene Membrane with Polyols for Removal of Boron Acid from Aqueous Solution
  • ISSN号:1004-9541
  • 期刊名称:《中国化学工程学报:英文版》
  • 时间:0
  • 分类:TQ325.14[化学工程—合成树脂塑料工业] O643.36[理学—物理化学;理学—化学]
  • 作者机构:[1]MOE Key Labortory of Macromolecular Synthesis and Functionalization, Department of Polymer Science andEngineering, Zhejiang University, Hangzhou 310027, China, [2]Department of Chemistry, Zhejiang University, Hangzhou 310027, China
  • 相关基金:Supported by the National Natural Science Foundation of China (50933006), and the National Basic Research Program ot China (2009CB623401).
中文摘要:

亲密关系膜被制作为硼酸由有基于乳糖的 polyols 的多微孔的聚丙烯膜(MPPM ) 的表面 functionalization 的酸移动。亲密关系基于特定的 complexation 在之间硼酸酸和糖类 polyols。一个 photoinduced 接枝化学药品反应序列被用来准备这些亲密关系膜。Poly (2-aminoethyl methacrylate hydrochloride )[poly (AEMA )] 是由紫外导致接枝聚合的 MPPM 的表面上的 grafted。在膜毛孔的 Grafting 被死设想剖面图 poly (AEMA ) 有荧光黄 disodium 的 -grafted MPPM 和有共焦的激光扫描的成像显微镜学。乳糖 ligands 能被随后的联合 covalently 在外部表面上并且在毛孔使不能调动,这被结束 poly (AEMA ) 与 lactobionic 酸(LA ) 。亲密关系膜的物理、化学的性质被扫描电子显微镜学和 Fourier 变换 Infrared/Attenuated 全部的折射光谱学(FT-IR/ATR ) 的地排放描绘。3-Aminophenyl 硼酸酸(3-APBA ) 被 lactose-functionalized MPPM 的一单个片在一个动态过滤系统从水的答案移开。结果证明 3-APBA 移动在碱的条件下面到达最佳的效率(39.5%)(pH 9.1 ) ,它能被增加 LA 的固定密度改进。因为,这些亲密关系膜的新生能容易通过酸硷的洗被认识到 complexation 硼酸酸和糖类 polyol 是可逆的。

英文摘要:

Affinity membranes are fabricated for boric acid removal by the surface functionalization of microporous polypropylene membrane (MPPM) with lactose-based polyols. The affinity is based on specific complexation between boric acid and saccharide polyols. A photoinduced grafting-chemical reaction sequence was used to prepare these affinity membranes. Poly(2-aminoethyl methacrylate hydrochloride) [poly(AEMA)] was grafted on the surfaces of MPPM by UV-induced graft polymerization. Grafting in the membrane pores was visualized by dying the cross-section of poly(AEMA)-grafted MPPM with fluorescein disodium and imaging with confocal laser scanning microscopy. It is concluded that lactose ligands can be covalently immobilized on the external surface and in the pores by the subsequent coupling of poly(AEMA) with lactobionic acid (LA). Physical and chemical properties of the affinity membranes were characterized by field emission scanning electron microscopy and Fourier Transform Infrared/Attenuated Total Refraction spectroscopy (FT-IR/ATR). 3-Aminophenyl boric acid (3-APBA) was removed from aqueous solution by a single piece of lactose-functionalized MPPM in a dynamic filtration system. The results show that the 3-APBA removal reaches an optimal efficiency (39.5%) under the alkaline condition (pH 9.1), which can be improved by increasing the immobilization density of LA. Regeneration of these affinity membranes can be easily realized through acid-base washing because the complexation of boric acid and saccharide polyol is reversible.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
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  • 被引量:385