以LaCoO3/K2CO3/CeZrO2为催化剂,分别采用程序升温脱附(TPD)、程序升温表面反应测试(TPSR)和以H2为还原剂的NOx存储-还原循环试验,研究了催化剂存储NOx的热稳定性以及NOx存储还原的性能,并分别对反应温度、还原时间和还原剂浓度这些影响因素进行了讨论.结果表明:LaCoO3/K2CO3/CeZrO2具有良好的储存和脱附再生性能,H2有较强的还原能力,在340~400℃下NOx转化率均为70%~80%,这些非常有利于降低发动机在实际工况下排放的NOx.
To investigate NOx thermal storage and NOx storage/reduction (NSR) performance with H2 as reduetant, perovskite catalysts were studied hy using the temperature programmed desorption and temperature programmed surface recation method. Storage experiments and storage-reduction experiments were conducted on a simulation bench, which provided some insight into the influence of reaction temperature, reduction time, and using H2 as reductant. The result indicated that LaCoO3/K2CO3/CeZrO2 perovskite catalyst processed good NOx storage and reduction property. A NOx conversion ratio of 600/00 to 800/00 can be achieved between 350 ℃ and 400 ℃, which could help to reduce NO, in high condition.