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中文摘要：
以[（bpca）Fe（CN）3]^-（bpca=二（2-吡啶羰基）酰胺阴离子）为构筑基元,设计合成了2个新颖的3d-4f异金属配合物,{[（bpca）Fe（CN）3Pr（H2O）5]Cl2}n（1）和{[（bpca）2Fe2（CN）6Pr（H2O）6]Cl.4H2O}n（2）,并测定了它们的晶体结构。化合物1的晶体属正交晶系,Pnma空间群;而化合物2属三斜晶系,P1^-空间群。在这2个化合物中,[（bpca）Fe（CN）3]^-和[Pr（H2O）x]^3＋（1,x=5;2,x=6）交替排列形成一维链状结构,并通过π-π堆积作用、氢键作用及分子间短距离相互作用形成三维网络结构。
英文摘要：
Two 3d-4f bimetallic complexes,{[（bpca）Fe（CN）3Pr（H2O）5]Cl2}n（1） and {[（bpca）2Fe2（CN）6Pr（H2O）6]Cl·4H2O}n（2）（bpca=bis（2-pyridylcarbonyl）amidate anion）,have been synthesized and their crystal structures were dete-rmined.Complex 1 crystallizes in the orthorhombic space group Pnma while complex 2 is in the triclinic space group P1.Both complexes possess novel one-dimensional（1D） chain structures with alternating arrays of [（bpca）Fe（CN）3]^-and [Pr（H2O）x]^3＋（x=5 for 1 and 6 for 2） fragments.They exhibit 3D supramolecular architectures through π-π stack-ing interactions,hydrogen bonds and short-distance intermolecular interactions.
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