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中文摘要：
按照原有计划，以合成化学为基础，根据电荷转移和超分子组装原理，深入开展了与信息存储等高新技术材料密切相关的光电功能配合物的研究，探讨分子材料中结构、机理与物理和化学功能的关系。在分子磁性半导体、单分子（单链）磁体、分子多铁体和手性磁体和分子导线等功能材料研究中取得了一些重要进展。如通过对TTF骨架进行微妙修饰，同时引入磁、电等多种功能，获得了含四硫富瓦烯衍生物并具有铁磁相互作用的二价钴一维配位聚合物，合成了含电活性多硫配体并具有单分子磁体行为的系列簇合物；成功合成了系列手性磁体、具有磁各向异性的多铁性金属有机簇合物和具有单链磁体行为的多铁性金属配合物。在本项目支持下，发表SCI论文61篇，其中影响因子大于3的有29篇。申请专利5项。国际学术会议邀请或者主题报告15次，国内会议大会或者邀请报告11次。本人担任了第二届亚洲配位化学会议组委会副主席、秘书长(2009年)，主持并完成了国家重大科学研究计划项目"分子及自旋体系中的量子调控"；入选教育部长江计划特聘教授(2009年)。毕业生中获全国优秀博士学位论文提名奖一篇(2010年)。
结论摘要：
英文主题词Metal Complexes; Molecular Design; Information Storage; Single-Molecule Magnets; Multifunctional Molecular Materials
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期刊论文
Syntheses, crystal structures, and electrochemical properties of transition metal complexes with new
Syntheses, structures, and properties of tricarbonyl rhenium(I) heteronuclear complexes with a new b
Syntheses, structures, and electrochemical and magnetic properties of rectangular heterobimetallic c
Rhenium(I) tricarbonyl complexes with new pyridine ligands containing crown ether-annelated or anthr
Syntheses and crystal structures of two one-dimensional 3d-4f heterobimetallic complexes based on [F
Syntheses, structures, and magnetic properties of heterobimetallic complexes based on tetracyanometa
Rhenium(I) tricarbonyl complexes with bispyridine ligands attached to sulfur-rich core: Syntheses, s
Syntheses, Structures, and Properties of Tricarbonyl (Chloro) Rhenium(I) Complexes with Redox-Active
Syntheses, structures, and magnetic properties of 3d-4f heterometallic complexes constructed from py
Syntheses and physical properties of three-dimensional coordination polymers with the flexible tripo
Syntheses, structures and magnetic properties of heterobimetallic complexes based on a new tetracyan
Synthesis, structure and physical properties of the one-dimensional chain complex of tetrathiafulval
Synthesis and characterization of neutral iron(II) and ruthenium(II) complexes with the isocyanotrip
Metal-Organic Coordination Polymers Generated from Chiral Camphoric Acid and Flexible Ligands with D
New 3d-4f Heterometallic Coordination Polymers Based on Pyrazole-Bridged Cu(II)Ln(III) Dinuclear Uni
The synthesis and electrochemical properties of a new tetra-(crown-ether-thiafulvalene)-annulated ph
Syntheses, structures, and magnetic properties of heterobimetallic (Fe2MII)-M-III (M = Cu, Mn) chain
A Family of Polynuclear Clusters Containing Cyano-Bridged T-Shaped (Fe3MII)-M-III (M = Cu, Co, Mn) M
Coordination Polymers Assembled from 3,5-Pyrazoledicarboxytic Acid and Bis(triazolyl) Ligands: Chira
Self-Assembly of Metal-Organic Coordination Polymers Constructed from a Versatile Multipyridyl Ligan
Syntheses, Structures, and Physical Properties of Camphorate Coordination Polymers Controlled by Sem
Syntheses, Structures, and Magnetic Properties of Heterobimetallic Clusters with Tricyanometalate an
Syntheses, Structures, and Magnetic Properties of Two Kinds of Unique Heterometallic Chains with Mix
Syntheses, structures, and properties of tricarbonyl rhenium(I) heteronuclear complexes with the mul
Structures and physical properties of oligomeric and polymeric metal complexes based on bis(pyridyl)
Dinuclear rhenium(I) carbonyl complexes based on pi-conjugated polypyridyl ligands with tetrathiaful
Synthesis and properties of new pi-conjugated pyridine ligands with tetrathiafulvalene derivatives a
Syntheses, Characterization, and Properties of Rhenium(I) Tricarbonyl Complexes with Tetrathiafulval
Hexanuclear Fe(2)(III)Co(2)(III)M(2)(II) (M = Cu, Ni, Mn) clusters based on Klaui';s tripodal ligand
Syntheses, structures, and properties of metal complexes involving pi-conjugated tetrathiafulvalene-
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