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三氧化二铟/B元素掺杂的g-C3N4催化剂的制备及性能研究
  • ISSN号:1001-3865
  • 期刊名称:《环境污染与防治》
  • 时间:0
  • 分类:TQ174.42[化学工程—陶瓷工业;化学工程—硅酸盐工业]
  • 作者机构:[1]阜阳师范学院化学与材料工程学院,安黴阜阳236037, [2]环境污染物降解与监测安黴省重点实验室,安黴阜阳236037, [3]武汉理工大学化工与生命科学学院,湖北武汉430070, [4]武汉理工大学化工与生命科学学院,湖北武汉430070)
  • 相关基金:安徽省自然科学基金资助项目(No.1408085MB35、No.1608085MB34);安徽省高等学校省级自然科学研究项目(No.KJ20163046、No.KJ2014A191、No.2015KJ008);阜阳师范学院校企合作实践教育基地项目(No.20l3SJJD05);大学生创新创业训练计划项目(No.201510371011、No.AH201410371010);阜阳师范学院科研机构校级委托专项课题(No.2015HJJC01ZD).
中文摘要:

以三聚氰胺和四苯基硼酸钠为原料,采用热解法制备了B元素掺杂的g-C3N4催化剂(CNB),然后将其与In2O3复合,经过煅烧后制备了具有不同配比的In2O3/CNB,同时考察了In2O3/CNB降解甲基橙、亚甲基蓝的光催化活性。结果表明:(1)In2O3/CNB的光催化活性较In2O3均提高,其中In2O3、CNB质量比为0.10时In2O3/CNB的甲基橙、亚甲基蓝降解率均达到最高,分别为47.6%、73.5%。(2)加入清除剂(过氧化氢酶、对苯醌、异丙醇、草酸铵)后催化剂的光催化活性均有较明显的降低。·OH、h^+、·O2^-和H2O2在光催化过程中均起显著作用,特别是·O-2起最主要的作用。适量的In2O3与CNB复合可显著抑制光生电子和空穴对的复合,提高了光生电子和空穴对的分离效率,进而提高了In2O3/CNB的光催化活性。

英文摘要:

Using tripolycyanamide and tetrapheny sodium borate as the precursors respectively, the catalyst of boron element doped g-C3N4 (CNB) was prepared by a pyrolysis method. The In2O3 /CNB composite photocatalysts with various weight percents of In2O3 were successfully prepared by a calcination process. At the same time, the activities of photocatalytic degradation of methyl orange and methylene blue were evaluated with In2O3 /CNB as composite photocatalysts. The results indicate that: (1) the photocatalytic activities of In2O3/CNB were higher than ln203 , especially, when the quality ratio of ln203 to CNB was 0.10 decomposition rates of methyl orange and methyl-ene blue were the highest, and reached 47.6% and 73.5% respectively. (2) When scavengers (catalase, p-benzoquinone, isopropyl alcohol, ammonium oxalate) were joined, the photocatalytic activities of catalysts were obviously reduced. OH,h^+ , , O2 and H2〇2 were all significant role,especially ,O2 was the main role in the photocatalytic process. The recombination of photoproduction electrons and holes was significantly suppressed by the composite of the right amount of ln203 with CNB,the separation efficiency of electrons and holes was improved,and the photocata-lytic activities of In203/CNB were improved.

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期刊信息
  • 《环境污染与防治》
  • 北大核心期刊(2011版)
  • 主管单位:浙江省环境保护局
  • 主办单位:浙江省环境保护科学设计研究院
  • 主编:金均
  • 地址:中国杭州天目山路109号
  • 邮编:310007
  • 邮箱:hjwrfz@vip.163.com
  • 电话:0571-87986875 87998967
  • 国际标准刊号:ISSN:1001-3865
  • 国内统一刊号:ISSN:33-1084/X
  • 邮发代号:32-15
  • 获奖情况:
  • 全国自然科学类核心期刊,2000年获第一届全国环境类期刊评比一等奖,1997-1998年度优秀期刊二等奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:25102