采用柠檬酸络合法合成了系列纳米钙钛矿型La1-xAgxMnO3(x=0,0.05,0.1,0.2,0.3,0.4)复合氧化物,利用TG-DTA和XRD技术对该系列氧化物进行了结构表征,发现所制样品具有钙钛矿构型。并以其为光催化剂在荧光汞灯照射下水溶性染料进行降解实验,结果表明Ag^+掺杂使LaMnO3的催化活性得到了很大的提高,并且在掺杂量为5%时催化剂的活性达到最高。XPS结果表明系列La1-xAgxMnO3的光催化活性与表面吸附氧的含量有关。
Perovskite oxides La1-xAgxMnO3 were prepared by citric acid complex method and analyzed by TG-DTA and XRD. It shown that the construction of prepared samples is perovskite-type. Using a luminous Hg lamp as irradiator, the degradation experiments of various water-soluble dyes were carried out in the suspension system of La1-xAgxMnO3. The results show that the photo-catalytic activity of La1-xAgxMnO3 is improved notably because of doping of Ag and La0.95Ag0.05MnO3 is the best one. The result of XPS shows photo-catalytic activity of La1-xAgxMnO3 is relative with the chemical adsorbed oxygen on surface.