中文摘要：

通过RD496-Ⅲ型热导式微热量计测定了配合物Co（AHD）2Cl2液相生成反应的恒压反应焓,通过设计合理的热化学循环,计算了配合物的固相生成反应焓。通过相关化学过程的热力学研究,为进一步探讨配合物的生成反应实质及应用提供了热力学依据。

英文摘要：

The enthalpy changes of the liquid-phase reactions of formation（ΔrHmθ（l））are determined by an improved RD496-Ⅲ type microcalorimeter and the enthalpy changes of the solid-phase reactions of formation（ΔrHmθ（s））are calculated on the basis of a thermochemical cycle, researched the dynamics of its related chemical process, provided thermodynamics basis to further study on the formation reaction essence and application of the coordination compounds.