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NAE双子表面活性剂与SDBS/PAM/PAA的协同效应
  • 分类:O626.1[理学—有机化学;理学—化学]
  • 作者机构:[1]化学合成与污染控制四川省重点实验室,西华师范大学化学化工学院,四川南充637009
  • 相关基金:国家自然科学基金21176201;四川省科技厅项目(2009JY0062)
中文摘要:

评价了一种阳离子型双子表面活性剂溴化-1,4-二[(3-十二烷氧基酰基)吡啶]丁烷(NAE12—4—12)与普通阴离子表面活性剂十二烷基苯磺酸钠、聚丙烯酰胺(PAM)和聚丙烯酸(PAA)的协同作用.实验结果表明NAE12—4—12:SDBS=3:7时,复配效果最好,混合体系的cmc降至0.0031mmol/L,相对于纯NAE12—4—12双子表面活性剂溶液,降低2个数量级;γcmc降低至27.8mN/m,比纯水的张力低44mN/m;该表面活性剂和PAM、PAA的临界缔合浓度cac高于NAE12—4—12的临界胶束浓度cmc,同时混合体系的γcac远低于0.01%PAM及PAA溶液的1值,说明NAE12—4—12与这两种聚合物之间存在较强的相互作用.

英文摘要:

In this paper, the synergic effect between 1, 4 - bis (3 - (dodecyloxylacyl) pyridinium) tutane) bromide (designated as NAE12 -4 -12) and sodium dodecyl benzene sulfate (SDBS), polyacrylamide (PAM) polyaerylic acid (PAA) have been studied. The results show that there is good synergic effect between NAE12 -4 - 12 and SDBS at NAE12 -4 - 12 :SDBS = 3:7. The cmc of the mixture of NAE12 -4 - 12 and SDBS is 0. 0031 mmol/L, which are two orders lower than that of NAE12 -4 - 12 solution free of SDBS. The value of-ycme reduces to 27.8 mN/m, which decreased by 44 mN/m compared with that of pure water. The critical aggregation concentrations of NAE12 -4 - 12 with PAM or PAA are higher than cme of NAE12 -4 - 12, and the γcat of mixture system is much lower than that of 0.01% PAM or PAA, suggesting that there is stronger interaction between NAE12 - 4- 12 and PAM/PPA.

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