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纳米WC增强Ni基合金喷熔层组织结构与抗磨粒磨损特性
  • ISSN号:1001-3660
  • 期刊名称:《表面技术》
  • 时间:0
  • 分类:TQ138.13[化学工程—无机化工]
  • 作者机构:武汉理工大学能源与动力工程学院,武汉430063
  • 相关基金:国家自然科学基金(51422507)
中文摘要:

目的 研究纳米WC对Ni基合金喷熔层抗磨粒磨损性能的影响。方法 采用扫描电镜、X射线衍射分析了氧乙炔火焰喷熔Ni基合金层和两种不同结构WC增强Ni基合金喷熔层的微观组织和相结构,并通过磨粒磨损试验平台对三种涂层进行磨损性能测试。结果 纳米WC粉末的加入,能有效提高喷熔层的宏观硬度。通过组织分析得出纳米WC增强Ni基喷熔层中除含有γ-(Ni,Cr)固溶体、Cr的碳化物、硼化物以及微米级WC颗粒之外,还含有一定量的纳米WC团聚体和少量高硬度的W2C相。磨粒磨损实验结果显示,纳米WC增强Ni基喷熔层的磨损失重分别为Ni60和NiWC35涂层失重的56%和73%。对比磨损后涂层的表面微观形貌可知,纳米WC颗粒在涂层中能有效降低磨粒压入喷熔层的深度,从而控制磨粒对喷熔层的犁削量。结论 纳米WC增强Ni基合金喷熔层中含有的γ-(Cr,Ni)固溶体、Cr(23)C6、Cr7C3、Cr3Ni2及未熔化的WC颗粒和WC脱碳形成的W2C等硬质相,使镍基自熔合金涂层的硬度有较大提高,同时也大大提高了涂层的抗磨粒磨损性能。

英文摘要:

The work aims to study effects of Nano-WC on abrasive wear resistance of Ni-based alloy spray-melted coating. Microstructure and phase structure of Ni-based alloy spray-melted in oxyacetylene flame as well as WC-reinforced Ni-based al- loy spray-melted coatings of two different structures were analyzed using scanning electron microscopy (SEM) and X-ray dif- fractometer (XRD). Meanwhile, wear resistance of the three coatings was tested using abrasive wear testbed. Addition of na- no-WC powder could effectively improve macro hardness of spray-melted coating. Nano-WC reinforced Ni-based alloy spray-melted coatings contained not only 7-(Ni, Cr) solid solutions, Cr carbide, boride and micro-scale WC particles, but also acertain amount of nano-WC particles and a small amount of high-hardness W2C phase. The results of abrasive test showed that wear weight loss of nano WC-reinforced layer was 56% of that of NiWC35 coating and 73% of that of Ni60. Compared with surface microstructure of the worn coating, nano-WC particles in the coating could effectively reduce depth of abrasive particles impressed into the spray-melted layer, so as to control ploughing amount of the abrasive particles on the spraying layer. Gener- ally, the by y-(Ni,Cr) solid solutions, Cr23C6, Cr7C3, Cr3Ni2, unmelted WC particles and hardness phases such as W2C formed by WC decarburization in the nano WC-reinforced Ni-based alloy spray-melted coating can greatly improve hardness and abrasive wear resistance of the coating.

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期刊信息
  • 《表面技术》
  • 中国科技核心期刊
  • 主管单位:中国兵器装备集团公司
  • 主办单位:中国兵器工业第五九研究所
  • 主编:吴护林
  • 地址:重庆市石桥铺渝州路33号
  • 邮编:400039
  • 邮箱:wjqkbm@vip.163.com
  • 电话:023-68792193
  • 国际标准刊号:ISSN:1001-3660
  • 国内统一刊号:ISSN:50-1083/TG
  • 邮发代号:78-31
  • 获奖情况:
  • 重庆市第四届期刊综合质量考评一级期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:11079