中文摘要：

allylic trifluoromethyl thioethers 的灵巧的准备被使用铜试剂完成。反应(bpy ) 有各种各样的 allylic 溴化物的 Cu (SCF3 ) 负担得起需要的 trifluoromethylthiolation 产品在对有高立体声的优秀收益好 -- 并且 regioselectivity。象烷基， alkoxy， trifluoromethyl， nitro，卤化物和 geranyl 那样的普通的功能的组很好被容忍。

英文摘要：

A facile preparation of allylic trifluoromethyl thioethers was achieved by using a copper reagent. The reaction of （bpy）Cu（SCF3） with various allylic bromides afforded the desired trifluoromethylthiolation products in good to excellent yields with high stereo- and regioselectivity. Common functional groups such as alkyl, alkoxy, trifluoromethyl, nitro, halides and geranyl are well tolerated.