中文摘要：

制备一系列介孔石墨相氮化碳负载氧化钒催化剂（V/CND）。通过N2吸-脱附、小角X射线散射、透射电镜、X射线衍射、拉曼光谱、傅里叶红外光谱、X射线光电子能谱等表征手段对V/CND材料的结构、形貌等理化性质进行表征。在苯甲醇选择氧化反应中,V/CND催化剂表现出较高的催化活性及良好的循环使用性。与传统载体材料（SBA-15、碳纳米管和活性炭）相比,V/CND催化剂具有更高的选择性（〉84%）。测试结果表明催化剂活性中心是分散的氧化钒物种。CND材料作为一种碱性载体可以有效地抑制苯甲醛的深度氧化。

英文摘要：

Mesoporous graphitic carbon nitride （CND） was prepared and used as a catalytic support to load vanadia. The obtained V/CND materials were characterized by several characterization techniques including N2 adsorption-desorption, SAXS, TEM, XPS, Raman, FT-IR, and XPS spectroscopy. In the selective ox- idation reactions of benzyl alcohol, the V/CND showed high catalytic performances and good recyclability, especially superior selectivities （〉 84%） to the values obtained over other vanadia catalysts supported on traditional materials （SBA-15, carbon nanotubes, and active carbon）. As revealed by FT-IR and XPS re- sults, the active sites were attributed to the dispersed vanadia species. More importantly, the basic chemi- cal environment of the CND support was regarded to effectively restrain the deep oxidation of benzalde- hyde.