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多壁碳纳米管/α-六噻吩双层OTFT气体传感器的制备及特性分析
  • ISSN号:1001-9731
  • 期刊名称:功能材料
  • 时间:2014
  • 页码:6041-6044+6050
  • 分类:O649[理学—物理化学;理学—化学]
  • 作者机构:[1]电子科技大学光电信息学院电子薄膜与集成器件国家重点实验室,成都610054
  • 相关基金:国家自然科学基金资助项目(61176066,61101031)
  • 相关项目:基于有机电致发光器件的气体传感器基础研究
中文摘要:

以多壁碳纳米管(multi-walledcarbonnanotubes,MWCNTs)和α-六噻吩(α-sexithiophene,α-6T)双层膜作为有源层,二氧化硅(SiO2)为绝缘层,钛/金(Ti/Au)作为电极,制备了沟道宽长比为640的有机薄膜晶体管(organicthin-filmtransistors,OTFT)气体传感器.测试了该传感器对痕量二氧化氮(NO2)气体的实时响应特性,并分析了NO2 气体对OTFT传感器阈值电压、载流子迁移率等多参数的影响.研究结果表明,基于MWCNTs/α-6T 的OTFT器件有较好的电学特性,载流子迁移率为3.0×10-2cm2/V·s;OTFT传感器对NO2 气体具有较高的响应率,响应和恢复时间短,能检测(0.2~1)×10-6 的痕量NO2 气体,且具有良好的重复性;同时可以利用阈值电压和载流子迁移率等多参数来表征响应结果.形貌分析结果表明双层敏感膜的特殊形貌有利于提高器件的气敏性能.

英文摘要:

Abstract: The multi walled carbon nanotubes (MW(NTs) and α-sexithiophene (α-6T) bilayer were taken as the active layer, and silicon dioxide (SiO2) was used as the insulating layer. Titanium..'aurum (Ti..'Au) were made as the electrode for the prepared OTFT gas sensor,of which the ratio of channel width to length was 640. The real time response characteristics of the sensor exposed to nitrogen dioxide (NO2) were tested, and the effect of NOe on the multi parameters of the OTFT sensor, such as threshold w)ltage and carrier mobility, was ana lyzed. The results showed that, the OTFT device based on MWCNTs/α 6T bilayer performed better electrical properties, and the carrier mobility reached 3. 0 × 1 0-2 cm2/V · s. The OTFT gas sensor showed the high re sponse when exposed to NO2 , and the time of response and recovery were short. The trace (0.2-1 )×1 0 -6 NO2 were detected and the sensor also had the good repeatability. It was feasible to take the multi parameters to present the gas response results. Morphology analysis showed that the special feature of the bilayer was helpful for improving the gas sensitivity.

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期刊信息
  • 《功能材料》
  • 北大核心期刊(2011版)
  • 主管单位:重庆材料研究院
  • 主办单位:重庆材料研究院
  • 主编:黄伯云
  • 地址:重庆北碚区蔡家工业园嘉德大道8号
  • 邮编:400707
  • 邮箱:gnclwb@126.com
  • 电话:023-68264739
  • 国际标准刊号:ISSN:1001-9731
  • 国内统一刊号:ISSN:50-1099/TH
  • 邮发代号:78-6
  • 获奖情况:
  • 2008、2011年连续获中国精品科技期刊,2010获重庆市双十佳期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:30166