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再生蚕丝的制备及其结构和性能初探
  • 期刊名称:高等学校化学学报,2007, 28(6), 1181-1185.
  • 时间:0
  • 分类:O636[理学—高分子化学;理学—化学] O629.7[理学—有机化学;理学—化学]
  • 作者机构:[1]复旦大学高分子科学系教育部聚合物分子工程重点实验室,上海200433
  • 相关基金:国家自然科学基金重点项目(批准号:20434010)和国家杰出青年科学基金(批准号:20525414)资助.
  • 相关项目:动物丝和丝蛋白的凝聚态基本问题及再生丝蛋白纤维高性能化的探索
中文摘要:

在制备高浓度高分子量蚕丝素蛋白水溶液的基础上,采用湿法纺丝技术,在一定条件下纺制出力学性能优于天然蚕(茧)丝的再生蚕丝纤维,其断裂强度及断裂伸长率分别达到0.5GPa和20%。扫描电镜观察结果显示:初生纤维具有典型的“皮芯”结构,而纤维内部则为疏松多孔的网状或蜂窝状结构;经过一定的后拉伸处理后,纤维的表面变得光滑,且内部结构也趋于致密。固体^13C核磁共振及拉曼光谱分析结果表明,后拉伸及热湿处理均有利于提高纤维内部β-折叠结构的含量,分子链的规整度和取向性也随之改善,从而使再生蚕丝纤维的力学性能得到进一步提高。

英文摘要:

Regenerated silk fibroin fibers with remarkable mechanical properties were successfully prepared via wet spinning technique, based on the high concentration and high molecular weight silk fibroin aqueous so-lution as spinning dope. With the observation of SEM, it could be found that the cellular structure may exist in the core of as-spun fibers. The regenerated silk fibers exhibited a smooth surface and dense structure after the post-drawn process. The NMR and Raman spectra results reveal that the β-sheet content increased with the in-crease of drawn ratios. It was also found that the steam-annealing can further improve the orientation of the macromolecular chains in the fibers. After the post treatment (both post-drawn and steam annealing), the breaking strength better than that o and the elongation at break can reach 0. 5 GPa and 22%, separately, which is close or even f natural silk (cocoon) fibers.

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