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污泥基活性炭吸附空气中甲醛的研究
  • ISSN号:1000-6923
  • 期刊名称:《中国环境科学》
  • 时间:0
  • 分类:X511[环境科学与工程—环境工程]
  • 作者机构:[1]湖南大学环境科学与工程学院,环境生物与控制教育部重点实验室,湖南长沙410082
  • 相关基金:国家自然科学基金资助项目(50878080); 长沙市科技重大专项(K0902006-31)
中文摘要:

以城市污水处理厂脱水污泥为原料,氯化锌为活化剂制备污泥基活性炭,采用BET比表面积测试、扫描电镜(SEM)、傅里叶红外光谱(FTIR)等方法研究其理化性能,利用动态吸附实验系统和蒸馏装置,将污泥基活性炭与选定的商业活性炭进行了甲醛吸附性能对比,并利用热重分析法研究了甲醛在各活性炭上的脱附情况.结果表明,污泥基活性炭对空气中浓度分别为498,0.41mg/m^3的甲醛均有很好的吸附效果,吸附量分别可达74.27,7.62mg/g,最大去除率分别为83.72%和89.56%,其吸附性能与选定的商业活性炭相当,特别是在处理浓度为0.41mg/m^3甲醛时超过选定的商业活性炭.该污泥基活性炭BET比表面积为509.88m^2/g,氮吸附等温线属于BDDT分类中的I-B型,表明其具有大量的超微孔和极微孔,更适用于低浓度甲醛的吸附.FTIR分析表明其表面含有各种含氮基团,特别是-NH2的存在,可能形成化学吸附中心,但从吸附甲醛后各活性炭的微商热重分析(DTG)曲线可以看出,各甲醛在活性炭上的吸附主要为物理吸附.

英文摘要:

sewage sludge based activated carbon(SSAC) was prepared by taking dewatered sewage sludge as raw material with ZnCl2 as activating agent.BET test,scanning electron microscopy(SEM) and Fourier transform infrared spectroscopy(FTIR) were utilized to analysis all of the Acs.Using dynamic adsorption system and distiller,adsorption performance of SSAC was compared with some commercial activated carbons(CACs),and the performances for desorption of formaldehyde in different activated carbons were investigated by using thermogravimetry.The adsorption capacity of SSAC,in formaldehyde concentration of 498,0.41mg/m^3,could achieve 74.27,7.62mg/g and the removal efficiency was 83.72% and 89.56 %,respectively,and such was comparable with CACs'.Especially,in 0.41mg/m^3,the result of SSAC exceeded that of CACs.The BET specific surface area of SSAC was 509.88m^2/g and its nitrogen adsorption isothermal curve belonged to I-B in the BDDT classification.SSAC had high proportion of micropores,which made it more suitable to adsorb low concentration formaldehyde.The FTIR spectra indicated that on the surface of SSAC,there were lots of nitrogen-containing groups,especially amino-groups.These groups might form chemical reaction centers.However,the Derivative thermogravimetry(DTG) curves of the activated carbons which had adsorbed formaldehyde indicated that the major adsorption of formaldehyde on activated carbons was physical adsorption.

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期刊信息
  • 《中国环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国环境科学学会
  • 主编:王文兴
  • 地址:北京市海淀区红联南村54号
  • 邮编:100082
  • 邮箱:zghjkx1981@126.com
  • 电话:010-62215145
  • 国际标准刊号:ISSN:1000-6923
  • 国内统一刊号:ISSN:11-2201/X
  • 邮发代号:2-572
  • 获奖情况:
  • 国家期刊提名奖,国家“双效”期刊,第三届中国科协优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:47702