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Lewis Base-Catalyzed Formation of α-Trifluoromethyl Alcohol from CF3SiMe3 and Carbonyl-Containing Compounds
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 分类：O623.4[理学—有机化学;理学—化学]
  • 作者机构：[1]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
  • 相关基金：Project supported by the National Natural Science Foundation of China （Nos. 20472106 and 20532040）.
作者： 祝诗发[1], 庞婉[1], 邢春晖[1], 朱仕正[1]
关键词： 醇, 有机合成, 有机化学, 催化反应, atom-economic, trifluoromethyl, organic synthesis
中文摘要：

路易斯底能从 CF3SiMe3 和包含羰基的混合物催化 -trifluoromethyl 酒精的形成。-trifluoromethyl 白酒能也被用来处于基本条件支持合成，这被发现。

英文摘要：

Lewis base could catalyze the formation of a-trifluoromethyl alcohol from CF3SiMe3 and carbonyl-containing compounds. It was found that the α-trifluoromethyl alcohol could also be used to promote the synthesis in basic conditions.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
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  • 被引量:175