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中文摘要：
本研究项目主要对当今有机氟化学前沿研究领域若干问题进行研究。进行有机氟化学中含氟功能材料合成及性质研究包括含氟烷基化卟啉的合成、金属化反应以及它们的物理和化学性质进行研究；研究含氟的卤代物如碘化物或溴化物和含杂原子分子如氮、氧及硫原子的分子间氢键、卤键等弱相互作用关系从而揭示分子间弱相互作用的一些本质问题；利用廉价的含氟砌块通过高立体选择性或区域选择性地化学转化合成一些在特定位置带有含氟基团的有机氟化合物，特别是含氟杂环化合物和具有生理活性的含氟天然产物类似物；不对称催化在有机氟化学中的应用，以达到反应的高立体选择性和区域选择性合成含氟的手性化合物。
结论摘要：
英文主题词Oganic fluorine chemistry;halogen bonding;heterocyclic compound;asymmetric catalysis
成果综合统计
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期刊论文
Practical and efficient synthesis of various meso-functionalized porphyrins via simple ligand-free n
Fluoroalkylation of porphyrins: Synthesis of porphyrins bearing double meso,beta-fused fluoroalkyl r
Lewis base-catalyzed formation of alpha-trifluoromethyl alcohol from CF3SiMe3 and carbonyl-containin
Study on the reaction of arsenic ylides with electron-deficient olefins containing one p-trifluorome
Study on the 1,3-dipolar cycloaddition reaction of 4-ethoxy-1,1,1-trifluoro-3-buten-2-one with nitri
Simple synthesis of 6-(trifluoromethyl)-2,4,5,6-tetrahydropyrazolo[3,4-b]pyran derivatives by one-po
One-pot preparation of fluorinated alpha-aminoalkyl phosphonates under microwave irradiation and sol
Highly stereoselective synthesis of trans-3-aryl-4-carbethoxy-2,3-dihydro-2-fur-2'-oyl-5-methylfuran
C-F bond activation by modified sulfinatodehalogenation: Facile synthesis and properties of novel te
Fluoroalkylation of aromatics: An intramolecular radical cyclization of 4-chloro-1, 1,2,2,3,3,4,4-oc
A general and efficient palladium-catalyzed intramolecular cyclization reaction of beta-brominated p
Synthesis of dendrimer-supported prolinols and their application in enantioselective reduction of ke
Allylation of aldehydes and imines: Promoted by reuseable polymer-supported sulfonamide of N-glycine
Unusual fluoroalkenylation of porphyrins: A highly stereoselective synthesis of 10,20-diaryl-5-[(E)-
Chemistry of difluorocarbene adducts: Stereospecific synthesis of conjugated fluoroolefins and 1,3-a
A novel example of vinylic S(RN)1: Reactions of 3,3-difluoro-1-iodo-2-phenylcyclopropene with thiola
Reactions of fullerenes with reactive methylene organophosphorus reagents: Efficient synthesis of or
Difluorocarbene chemistry: Synthesis of gem-difluorocyclopropenyl ketones and gem-difluorinated dihy
Synthesis of modular thiophene-oxazoline ligands and their application in the asymmetric phenyl tran
Asymmetric reduction of substituted indanones and tetralones catalyzed by chiral dendrimer and its a
Effective and recyclable dendritic catalysts for the direct asymmetric Michael addition of aldehydes
Stereoselective preparation of 1,2,4-oxadiazole derivatives substituted by pentafluorophenyl by 1,3-
A new route to Z-5-fluoro-2-methyl-1-(p-methylsulfinylbenzylidene)-3-indenylacetic acid and its X-ra
One-pot synthesis of N-protected alpha-amino aldehyde acetals from three-component reaction of fluor
Facile synthesis of fluorinated alpha-imino alkynes by the coupling reaction of imidoyl iodides with
The chemical transformation of beta-bromodifluoromethyl beta-enaminoketones: Synthesis of difluorome
Facile synthesis of alpha-fluoro, substituted amidines from imidoyl chlorides and some of its applic
Crystal structure of a supramolecular complex formed between 1-bromo-2-iodo-tetrafluoroethane and N,
Blaise reaction of ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate with nitriles: A convenient synth
Synthetic applications of ethyl 3-bromodifluoromethyl-3-benzyloxy-acrylate as a gem-difluorination b
Synthesis of nickel-salicylideneimines complexes and catalyzing cross-coupling reaction of aryl hali
Nucleophilic addition of ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate to imines: An effective ent
Stereoselective preparation of trifluoromethyl containing 1,4-oxathiolane derivatives through ring e
Rh-2(OAc)(4)-catalyzed formation of trans-alkenes from the reaction of aldehydes with perfluoropheny
Highly efficient and reusable dendritic catalysts derived from N-prolylsulfonamide for the asymmetri
Transition metal-catalyzed formation of CF3-substituted alpha,beta-unsaturated alkene and the synthe
Synthesis and hetero-Diels-Alder reactions of (E)-alpha-perfluoroalkanesulfonyl-alpha,beta-unsaturat
Unexpected formation of trifluoromethylated spiro or fused cyclic compounds from 4-ethyloxy-1,1,1-tr
Unprecedented Degradation of Nickel(II) 2,3,12,13-Tetrabromo-5,10,15,20-tetraarylporphyrins by the A
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected i
A novel pyrrolidinium ionic liquid with 1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethanesulfo
Concise synthesis of omega-fluoroalkylated ketoesters. A building block for the synthesis of six-, s
Pd-catalyzed direct arylation of 3-fluorofurans utilizing the neighboring effect of fluorine atom: f
Unexpected Reactions of Push-Pull N-Heterocyclic Carbene Derived from N-(4-Methoxyphenyl)-N-(4-nitro
Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ket
Highly Efficient Asymmetric Epoxidation of Electron-Deficient alpha,beta-Enones and Related Applicat
Enantioselective synthesis of multifunctionalized 4H-pyran derivatives using bifunctional thiourea-t
Synthesis of Substituted 5-(Pyrrolidin-2-yl)tetrazoles and Their Application in the Asymmetric Bigin
Facile Synthesis of Monofluoro gamma-Lactones and Pyrrolidine Derivatives via Electrophilic Fluorina
Study of the Reactions of Fluorine-Containing Amides with Aldehydes and the Structures of the Bisami
Efficient One-Pot Regioselective Synthesis of 2,3-Dibromo-5,10,15,20-tetraarylporphyrins from 5,10,1
Novel low-melting salts with donor-acceptor substituents as targets for second-order nonlinear optic
Stereoselective Synthesis of trans-2-thien-alpha-oyl-3-[(un)substituted phenyl]-4-acetyl-5-methyl-2,
Enantioselective catalytic epoxidation of alpha,beta-enones promoted by fluorous alpha,alpha-diaryl-
Synthesis of 3-Fluoro-2,5-Disubstituted Furans and Further Derivative Reactions to Access Fluorine-C
One-pot preparation of fluorinated propargylamines under microwave irradiation and solvent-free cond
BF3-promoted cyclization reaction of imines and salicylaldehyde with silyl enol ethers: unexpected f
Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the othe
A convenient one-pot synthesis of 2-(trifluoromethyl)-3,4,7,8-tetrahydro-2H-chromen-5(6H)-one deriva
Synthesis of Indoles via Diethylzinc-Mediated Intramolecular Hydroamination Reactions of Alkynyl Sul
Organocatalyzed Friedel-Craft-type reaction of 2-naphthol with beta,gamma-unsaturated alpha-keto est
An unexpected tandem enantioselective Michael addition/oxa-nucleophilic rearrangement reaction of be
Organocatalyzed Highly Enantioselective Michael Additions of Malonates to Enones by Using Novel Prim
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