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中文摘要：
本项目从我们自己的工作基础出发研究通过从金属交换、碳-氢键活化、氧化加成、环金属化等途径生成新型金属中间体，研究这些金属中间体与碳-碳双键、叁键，碳-氧双键的反应性，为多环化合物的生成提供高效合成方法学，发展有机合成化学，推动有机化学的发展。导向有机合成的金属有机化学一般分以下三个关键过程(1)金属中间体的生成；(2)通过金属中间体转换成与第二组份的反应生成新的金属中间体；(3)生成的金属中间体的淬灭。重视催化活性物种的再生,以设计催化反应。本项目研究的具体对象为有机硼试剂、简单芳烃、炔烃、亚烷基环丙烷和联烯等，根据我们已有的工作基础，这些化合物很容易发生金属化反应生成具有特定结构的含碳-新型金属过渡中间体，我们将基于这些金属中间体的反应性研究，发展有自己特色的金属有机化学。
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
General Au-Catalyzed Benzannulation towards Naturally Occurring Carbazole Alkaloids from Methoxyprop
Highly Regio- and Stereoselective Three-Component Nickel-Catalyzed syn-Hydrocarboxylation of Alkynes
Highly Regioselective Synthesis of 2,3,5-Trisubstituted Furans via Phosphine-
Catalyzed Ring-Opening
Organo-Selenium Induced Radical Ring-Opening Intramolecular Cyclization or Electrophilic Cyclization
Efficient Synthesis of 9-Tosylaminofluorene Derivatives by Boron Trifluoride-Catalyzed Aza-Friedel-C
Facile Cu(OTf)2-Catalyzed Preparation of 9-Tosylaminofluorene Derivatives from o-Arylated N-tosylben
Cationic Palladium-Catalyzed [5+2] Annulation of 2-Acylmethoxyarylboronic Acids and Allenoates: Synt
Intramolecular Cycloisomerization of Aryl-Substituted Alkylidenecyclopropanes via NHC Palladium-Cata
An Efficient Synthesis of Highly Substituted Furans via the Electrophilic Cyclization of 1-(1-Alkyny
Studies on Palladium-Catalyzed Enantioselective Cyclization of 3,4-Allenylic Hydrazines with Organic
An Efficient Synthesis of 2-Vinylic Cyclic 1,3-Alkadienes via the Cp*Ru(II)-Catalyzed Intermolecular
Highly Stereoselective Facile Synthesis of 2-Acetoxy-1,3(E)-alkadienes via a Rh(I)-Catalyzed Isomeri
Controllable Stereoselective Reaction of in-situ Generated Magnesium Dienolate Intermediates with Di
Efficient Highly Selective Synthesis of Methyl 2-(Ethynyl)alk-2(E)-enoates and 2-(1’-Chlorovinyl)alk
One-Pot Construction of Aza- or Oxa-Bridged Benzocycloheptanes from Readily Available 2,3-Allenyl Ma
Palladium-Catalyzed Three-Component Reaction of 2,3-Allenyl Amines, Isocyanates, and Organic Halides
Palladium-Catalyzed Three-Component Tandem Cyclization Reaction of 2-(2,3-Allenyl)acylacetates, Orga
Studies on the Factors Controlling the Stereoselectivity in Electrophilic Iodocyclization of Alkylid
Cationic Pd(II)/Bipyridine-Catalyzed Conjugate Addition of Arylboronic Acids to ???-Disubstituted En
Synthesis of Indoles via Palladium-Catalyzed C-H Activation of N-Aryl Amides Followed by Coupling wi
Pd(OAc)2-Catalyzed Tandem Reaction for the Synthesis of Indol-3-yl Substituted 1H-Isochromenes and 1
Synthesis of Polysubstituted Furans Based on a Stepwise Sonogashira Coupling of (Z)-3-Iodoalk-2-en-1
PdCl2/NaI-Catalyzed Homodimeric Coupling-Cyclization Reaction of 2,3-Allenols: An Efficient Synthesi
An Efficient Synthesis of Allenyl Perfluoroalkyl Ketones from Mono-1,2-Addition-Elimination Reaction
Carbon-Carbon Double-Bond Isomerization and Diels-Alder Reaction of Dimethy 5-Methylene-4-isopropyli
A Multicomponent Reaction of Arynes, Isocyanides, and Terminal Alkynes: Highly Chemo- and Regioselec
Facile Synthesis of Polycyclic Fluorene Derivatives via A Palladium-catalyzed Coupling, Propargyl-al
One-Pot Facile Synthesis of Substituted Isoindolinones via an Ugi Four-Component Condensation/Diels?
An Efficient Synthesis of Polysubstituted Tetrahydrofuran and Indene Derivatives Via The Lewis Acid-
Multicomponent reactions of pyridines, α-bromo carbonyl compounds and silylaryl triflates as aryne p
Cupric Halide-Mediated Intramolecular Halocyclization of N-Electron-Withdrawing Group-Substituted 2-
Cationic Pd(II)-Catalyzed Tandem Reaction of 2-Arylethynylanilines and Aldehydes: An Efficient Synth
Cascade Nucleophilic Addition?Cyclic Michael Addition of Arynes and Phenols/Anilines Bearing Ortho α
Selectivity Manipulation of Bicyclization Reactions of 1,5-Bis(1,2- allenylketone)s: Pd versus Rh an
An Efficient Approach to Substituted 1,5,7,8,9-Pentahydrocyclopenta[h]-2-Benzopyran-3-one Derivative
Highly Regio- and Stereoselective Synthesis of Nine- to Twelve-Membered Cyclic Compounds by a Pd0-Ca
Halohydroxylation of alkylidenecyclopropanes using N-halosuccinimide (NXS) as the halogen source: an
PdI2-Catalyzed Coupling- Cyclization Reactions Involving Two Different 2,3-Allenols: An Efficient Sy
Pd(OAc)2-Catalyzed Cyclization of 2,3-Allenoic Acids in the Presence of Terminal (,β-Unsaturated Alk
Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantiose
Pd(II)-catalyzed annulation of N-benzyl-N-aroylmethyl-2-alkynamides with arylboronic acids: an effic
Unexpected Pd-catalyzed Coupling, Propargyl-Allenyl Isomerization and Alder-Ene Reaction: Facile Syn
Facile Synthesis of Tetrahydrofurans from Cycloadditions of Vinylidenecyclopropanes with Aldehydes a
Solid-Phase Synthesis of 2,5-Dihydro-1H-pyrroles, 1,3-Dioxo-2,3,5,7a-tetrahydro-
1H-pyrrolo[1,2-c]im
Ligand Effects on the Pd-Catalyzed Cross-Coupling Reaction of 3-Iodoalk-2-enoates with Propargyl/1,2
Palladium-Catalyzed Synthesis of 1,3,4-Alkatrien-2-yldihydrofurans from 2,3-Allenylacetylacetates an
The Reaction of Carboxylic Acid Esters with RfMgBr: A Convenient Synthesis
of Perfluoroalkyl Ketones
An Efficient Synthesis of Polysubstituted Naphthalene Derivatives by Gold-Catalyzed Cyclization of 1
Synthesis of A New Spiro-BOX Ligand and Its Application in Enantioselective Allylic Cyclization Base
Cationic Palladium Complex Catalyzed Diastereo- and Enantioselective Tandem Annulation of 2-Formylar
Substrate-Controlled Selective Proximal and Distal C-C Bond Cleavage via Lewis Acid Mediated O-Acyla
Iodohydroxylation of Alkylidenecyclopropanes. An Efficient Synthesis of Iodocyclo propylmethanol and
Controllable Cyclizations Reactions of 2-(2’,3’-Allenyl)acetylacetates Catalyzed by Gold and Palladi
Neighboring Group Participation of Phosphine Oxide Functionality in the Highly Regio- and Stereosele
Halohydroxylation of 1-Cyclopropylallenes: An Efficient and Stereoselective Method for the Preparati
Cationic Palladium(II)-Catalyzed Highly Enantioselective Tandem Reactions of ortho-Boronate- Substit
Palladium-Catalyzed Three-Component Cascade Cyclization Reaction of Bisallenes with Propargylic Carb
Unexpected Formation of (E)-4-Alkene 1,3-Diketones from the Three-Component Reaction of Lithium Sele
A Facile Access to Medium- and Large-Size Naphthalena- carbocycles via Lewis Acid Mediated Ring-Expa
Facile Synthesis of Tetrahydro-1H-isoindolones via a Sequential Three-Component Copper-Catalyzed Cou
Facile and Efficient Synthesis of Hydrophenanthren-1(2H)-ones and Naphtho [2,1-c]furan-3(1H)-ones by
Highly Regioselective Synthesis of Trisubstituted Allenes via Lithiation of 1-Aryl-3-alkylpropadiene
Difunctional Additions to1-Cyclopropylallenes: An Efficient and Stereospecific Method for the Synthe
Unique reactivity of Grignard reagents towards cyclopropenylcarboxylates—
highly selective carbon–ca
Palladium(II)-Catalyzed Highly Stereoselective Sandwich-Type Triple Cyclization Reaction of 1,5-Bisa
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