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中文摘要：
功能配位化学是当前化学研究的前沿领域之一。本群体将通过与材料、生物、环境等多学科的交叉，以物理功能为导向，构建特定结构和复杂分子有序体，研究分子间作用的协同和位点识别的本质以及组装规律，实现对分子结构和功能的预测和控制。探索在分子离子探针、分子开关、分子机器等方面的应用。开展具有光、电、磁性等功能配合物的研究，阐明结构与性能的关系，研制在高新技术中具有应用前景的分子固体和分子材料。开展离子识别与金属酶模拟及金属药物的设计、合成和筛选工作，探讨金属配合物在疾病诊断、治疗以及调控生命过程中的作用，开发新型铂类和金属茂化合物类药物。通过优势互补、紧密合作，形成一支在国际上有一定影响的功能配合物研究队伍。2002年以来,本群体成员共发表SCI论文350 余篇(其中影响因子大于3论文约108篇)，这些论文被他人引用共1720多次，获国家自然科学二等奖一项，教育部提名国家科学技术奖自然科学奖三项。
英文摘要：
Functional Complexes；Opto-electronic property；Magnetic property；adsorption property；Bio-coordination
结论摘要：
本群体结合国内外相关研究的发展趋势，发挥群体在多学科方面的优势，紧密合作，在与材料科学和生命科学密切相关的功能配位化学和分子材料领域深入开展基础研究工作，在新型配位化合物体系的设计与合成、光电功能配合物的可控合成及性质规律研究、金属离子识别、金属酶模拟及金属药物的设计等方面取得了一系列重要进展。代表性的成果包括1）利用配位化学和晶体工程学的原理和方法与不同配位构型的过渡金属、稀土金属盐反应构筑新型配位化合物及聚合物，有序定向地组装特殊的柔性或刚性多维体系以及类四级结构。研究其结构以及对气体或溶剂分子的吸附、分子及离子的识别、手性对映体的拆分等性能，探讨组装规律及对孔道(洞)结构和大小的调控，为发展多孔材料、分子/离子探针以及分子器件提供基础。进一步开展纳米材料的控制合成和组装，力争实现纳米材料的绿色化合成，探索纳米材料结构与性质的关系，开发纳米材料及复合杂化材料的实际应用。2）通过调变有机配体和金属离子的电子结构和配位构型，构建各种过渡金属配合物，获得具有预期结构和功能的新化合物。研究光诱导电子转移和能量传递基本过程，探索与能源相关的光电转换和能量存储材料，如太阳能利用、传感器和光电转换信息材料等。对于具有磁性中心的配位聚合物体系，利用磁性分子工程，调变金属离子和配体间交换和自旋取向，组装以高转变温度为目标的具有特定结构的多维分子铁磁性体系。通过对磁性分子在空间中排布方式的调控，发现低维配合物型分子磁体的形成过程和磁性的规律，探索新的具有顺磁基态的单分子磁体、单链磁体和具有抗磁基态的量子自旋体系。研究由手性导致铁电、手性磁体、铁弹等性质；研究磁性半导体、分子多铁体的多功能性以及各种功能之间的耦合，为分子材料和器件的构建提供基础。3）设计、合成对DNA 具有序列、构型、区域等选择性识别作用，以及具有水解切割DNA、RNA 能力的金属配合物，进行人工核酸酶的筛选及性能研究，为发现和开发新型金属药物、核酸结构探针以及新型、高效人工核酸酶奠定坚实的化学基础；发展近红外激发或双光子激发比例计量荧光探针,尝试实现活体定量定向/深度造影；发展其他生命相关离子、分子的荧光探针，明确一些细胞生理过程的相关性和因果关系。通过设计和制备多个系列新型配体及其铂配合物，研究了它们的抗肿瘤活性，为获得具有自主知识产权的铂抗癌药物奠定了基础。
成果综合统计
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期刊论文
Construction of coordination frameworks based on 4-imidazolyl tecton 1,4-di(1H-imidazol-4-yl)benzene
An excitation ratiometric Zn2+ sensor with mitochondria-targetability for monitoring of mitochondria
Cytotoxic palladium(II) complexes of 8-aminoquinoline derivatives and the interaction with human ser
A microporous metal-organic framework with FeS2 topology based on Zn-6(mu(6)-O) cluster for reversib
Zinc(II) and Cadmium(II) Complexes with Rigid 3,3 ',5,5 '-Tetra(1H-imidazol-1-yl)-1,1 '-biphenyl and
Coordination polymers with mixed 4,4 '-bipyridine-2,29,6, 6 '-tetracarboxylate and imidazole-contain
Microwave-assisted synthesis and photocatalytic properties of flower-like Bi2WO6 and Bi2O3-Bi2WO6 co
Bi2MoO6 microstructures: controllable synthesis, growth mechanism, and visible-light-driven photocat
Improvement of dye-sensitized solar cells' performance through introducing suitable heterocyclic gro
Syntheses, Characterization, and Properties of Functionalized 9,10-Bis(1,3-dithiol-2-ylidene)-9,10-d
Synthesis, crystal structures, and photoluminescence of two novel zinc coordination polymers built f
Synthesis, Structure, and Magnetic Properties of Three 1D Chain Complexes Based on High-Spin Metal-C
Linear Heterocyclic Aromatic Fluorescence Compounds Having Various Donor-Acceptor Spacers Prepared b
Synthesis, photoluminescence and computational study of rhenium(I) diimine complexes with 1,3,4 oxad
The First Observation of One-Dimensional Naphthalenediimidato-Based Transition-Metal Coordination Po
Syntheses, Structures, and Magnetic Properties of seven-coordinate Lanthanide Porphyrinate or Phthal
Seven-Coordinate Lanthanide Sandwich-Type Complexes with a Tetrathiafulvalene-Fused Schiff Base Liga
A porous metal-organic framework based on Zn6O2 clusters: chemical stability, gas adsorption propert
Synthesis and characterization of d(10) metal complexes with mixed 1,3-di(1H-imidazol-4-yl)benzene a
A reversible ratiometric sensor for intracellular Cu2+ imaging: metal coordination-altered FRET in a
Cobalt and Manganese Diphosphonates with One-, Two-, and Three-Dimensional Structures and Field-Indu
Zinc(II) and Cadmium(II) Complexes with 1,3,5-Benzenetricarboxylate and Imidazole-Containing Ligands
Syntheses, Photoluminescence, and Electroluminescence of Iridium(III) Complexes with Fluorinated 2-P
Syntheses, Structures, Photochemical and Magnetic Properties of Novel Divalent Cd/Mn Coordination Po
Zinc(II) and cadmium(II) coordination polymers mediated by rationally designed symmetrical/asymmetri
A platinum anticancer theranostic agent with magnetic targeting potential derived from maghemite nan
Unusual group migration and C(sp(3))-H activation leading to stable metallacycles in the reactions o
Synthesis and photoluminescence properties of rhenium(I) complexes based on 2,2 ':6 ',2 ''-terpyridi
The Synthesis and Properties of Free-Base 14 Triphyrin(2.1.1) Compounds and the Formation of Subporp
Functionalized oligothiophene-based heterocyclic aromatic fluorescent compounds with various donor-a
Metal complex with terpyrindine derivative ligand as highly selective colorimetric sensor for iron(I
Syntheses and photoluminescence properties of rhenium(I) complexes based on dipyrido 3,2-a:2 ',3 '-c
Controlled Synthesis of Heterotrimetallic Single-Chain Magnets from Anisotropic High-Spin 3d-4f Node
Synthesis, characterization and crystal structure of one Co(II) complex with 4,4 '-bisimidazolylbiph
An Oxalate-Bridged Copper(II) Dimer and a Mononuclear Cobalt(III) Azide Complex Containing N-Nitrile
Metal-organic frameworks with N-(4-pyridylmethyl)iminodiacetate ligand: Synthesis, structure and sor
Synthesis, characterization, and optical properties of new metal complexes with the multi-sulfur 1,2
Metal Complexes Based on Tetrathiafulvalene-Fused pi-Extended Schiff Base Ligands - Syntheses, Chara
Cell-Compatible Fluorescent Chemosensor for Zn2+ Based on a 3,8-Extended 1,10-Phenanthroline Derivat
Exciton Coupling Analysis and Enolization Monitoring by Vibrational Circular Dichroism Spectra of Ca
Syntheses, characterization and properties of oxo-centered triruthenium cluster with tetrathiafulval
Coordination polymers constructed by diverse metal centers and the rigid ligand 3,5-di(1H-imidazol-1
Synthesis, structure, novel topology and reversible crystal-to-amorphous transformation of calcium c
Azo-hydrazone tautomerism by in situ Cu-II ion catalysis and complexation with the H2O2 oxidant of C
Two stacked 2D(chiral)/2D(chiral) -> 2D(achiral) sheets based on V-shaped imidazolyl ligand and flex
Iron(II) Complexes Based on pi-Conjugated Terpyridine Ligands with Tetrathiafulvalene or Its Radical
Room temperature solution-phase synthesis of flower-like nanostructures of Ni-3(BTC)(2)center dot 12
Large-scale synthesis of porous yolk-shell structured In2O3 using indium(III) benzophenone-4,4 '-dic
Size-controlled indium(III)-benzenedicarboxylate hexagonal rods and their transformation to In2O3 ho
Synthesis, photoluminescence and electrochemiluminescence of ruthenium(II) polypyridyl complexes bas
Syntheses, structures, luminescent and magnetic properties of a novel class of metal complexes const
Antimicrobial activity of a ferrocene-substituted carborane derivative targeting multidrug-resistant
Synthesis, structure, photophysical and electrochemical properties of series of new fac-triscyclomet
Systematic Investigation of the Influences of Solvent and Temperature on the Formation of Three Co-C
Improving nuclease activity of copper(II)-terpyridine complex through solubilizing and charge effect
Template-free synthesis of mesoporous NaTbF4 and NaTbF4:Eu nano-rice and their luminescence properti
Construction of a series of metal-organic frameworks with a neutral tetradentate ligand and rigid ca
Comparative structural and spectral analyses for mononuclear and dinuclear metal complexes of 2-thio
Noncovalent Interactions between a Trinuclear Monofunctional Platinum Complex and Human Serum Albumi
Two Porous Zinc Coordination Polymers with (10,3) Topological Features Based on a N-Centered Tripoda
A new "turn-on" chemodosimeter for Hg2+: ICT fluorophore formation via Hg2+-induced carbaldehyde rec
DNA cleavage behavior of a new p-xylyl spaced bisCu(BPA)Cl-2 complex: the steric effect of a bulky p
Structural Characterization, Infrared Spectroscopy, and Theoretical Calculations for B(C6F5)(3)-Stab
Biomolecule-Assisted Construction of Cadmium Sulfide Hollow Spheres with Structure-Dependent Photoca
A mononuclear Mn2+ complex based on a novel tris-(ethyl acetate) pendant-armed tetraazamacrocycle: E
Carborane enhanced two-photon absorption of tribranched fluorophores for fluorescence microscopy ima
Syntheses, crystal structures and properties of dinuclear hydrido-tris(3,5-diphenylpyrazol-1-yl)bora
Chiral and Noncentrosymmetric Metal-Organic Frameworks Featuring a 2D -> 3D Parallel/Parallel Inclin
Reactivity of a 16-Electron CpCo Half-Sandwich Complex Containing a Chelating 1,2-Dicarba-closo-dode
In vitro and in vivo imaging application of a 1,8-naphthalimide-derived Zn2+ fluorescent sensor with
Synthesis, characterization and crystal structure of one Mn(II) complex with 4,4 '-bisimidazolylbiph
Cuprous iodide coordination polymers (CuI)(x)(L)(y)center dot z(solvent) built on linear thioether l
Fast preparation and growth mechanism of erythrocyte-like Cd2Ge2O6 superstructures via a microwave-h
Synthesis and crystal structure of trinuclear zinc coordination polymer based on a triangle flexible
D-D-pi-A organic dyes containing 4,4 '-di(2-thienyl)triphenylamine moiety for efficient dye-sensitiz
Vapor-induced chiroptical switching in chiral cyclometalated platinum(II) complexes with pinene func
Helical silver(I) coordination polymer with oxazoline-containing ligand: Structure, non-linear and f
Syntheses, characterization and properties of rhenium(I) tricarbonyl complexes based on tetrathiaful
Cobalt-Mediated Selective B-H Activation and Formation of a Co-B Bond in the Reaction of the 16-Elec
Synthesis and photovoltaic performances of donor-pi-acceptor dyes utilizing 1,3,5-triazine as pi spa
Nickel ions inducing growth of high-index faceted alpha-Fe2O3 and their facet-controlled magnetic pr
pH-Dependent cobalt(II) frameworks with mixed 3,3 ', 5,5 '-tetra(1H-imidazol-1-yl)-1,1 '-biphenyl an
Two pairs of isomorphism and two 3D metal-organic frameworks based on a star-like ligand tri(4-pyrid
Ion-induced diversity in structure and magnetic properties of hexacyanometalate-lanthanide bimetalli
Graphene oxide induced growth of one-dimensional fusiform zirconia nanostructures for highly selecti
Fast preparation of Bi2GeO5 nanoflakes via a microwave-hydrothermal process and enhanced photocataly
Synthesis, structures and magnetic properties of cyano-bridged 3d-4f rectangular tetranuclear Fe(2)(
Assembling 1D magnetic chain based on octacyanotungstate(V) and Cu(2)L(2)Ln sub-building units (Ln =
Syntheses, Characterization, and Properties of Three-Dimensional Pillared Frameworks with Entangleme
Reactivity of the 16-electron CpCo half-sandwich complex containing a B(3,6)-disubstituted o-carbora
Coplanar Bithiazole-Centered Heterocyclic Aromatic Fluorescent Compounds Having Different Donor/Acce
Synthesis and characterization of efficient luminescent materials based on 2,1,3-benzothiadiazole wi
DNA microarray fabricated on poly(acrylic acid) brushes-coated porous silicon by in situ rolling cir
Synthesis and Crystal Structure of a Dicuclear Cobalt Complex Consisting of 2, 2 '-Bipyrimidyl and D
New high-nuclearity manganese clusters containing mixed chelating ligands: Syntheses, crystal struct
Facile synthesis of zinc(II)-carboxylate coordination polymer particles and their luminescent, bioco
Syntheses, structures, sorption and magnetic properties of copper(II) frameworks with varied topolog
Assembly of {Mn-2(salen)(2)}(2+) Dimers by Cyclic V4O124- Clusters: A 3D Compound with Open-Framewor
Co(II) and Ni(II) complexes based on anthraquinone-1,4,5,8-tetracarboxylic acid (H(4)AQTC): canted a
An Unprecedented Homochiral Metal-Organic Framework Based on Achiral Nanosized Pyridine and V-Shaped
Mono- and Dinuclear Co/Ni Complexes Bearing Redox-Active Tetrathiafulvaleneacetylacetonate Ligands -
Syntheses, Photoluminescence, and Electroluminescence of a Series of Iridium Complexes with Trifluor
Structural Diversity and Properties of Coordination Polymers Built from a Rigid Octadentenate Carbox
Construction of lanthanide metal-organic frameworks with highly-connected topology based on a tetrap
Syntheses, structures and catalytic activities of ruthenium (II) carbonyl iodide complexes with CNC-
Series of Metal-Organic Frameworks Including Novel Architectural Features Based on a Star-like Tri(4
Homochiral ferroelectric three-dimensional cadmium(II) frameworks from racemic camphoric acid and 3,
Tricarbonyl Mono- and Dinuclear Rhenium(I) Complexes with Redox-Active Bis(pyrazole)-Tetrathiafulval
Anion-selectivity of cationic cluster-organic nanospheres based on a nest-shaped MS4Cu3X3 clustermon
Comparative photophysical properties between bicyclo 2.2.2 octadiene (BCOD)- and benzo-fused free-ba
Construction of three-dimensional metal-organic frameworks in the presence of a tetrahedral ligand a
An interesting molecular-assembly of beta-cyclodextrin pipelines with embedded hydrophilic nickel ma
A specific chemodosimeter for fluoride ion based on a pyrene derivative with trimethylsilylethynyl g
Chiral 3D/3D hetero-interpenetrating framework with six kinds of helices, 3D polyrotaxane and 2D net
Comparisons between azo dyes and Schiff bases having the same benzothiazole/phenol skeleton: Synthes
Three 2D/2D -> 2D or 3D Coordination Polymers: Parallel Stacked, Interpenetration, and Polycatenated
Water Stable Metal-Organic Framework Evolutionally Formed from a Flexible Multidentate Ligand with A
Microwave-assisted hydrothermal synthesis, growth mechanism and photocatalytic properties of pancake
Self-assembled hollow rare earth fluoride alloyed architectures with controlled crystal phase and mo
Six New Metal-Organic Frameworks Based on Polycarboxylate Acids and V-shaped Imidazole-Based Synthon
Cobalt and copper phosphinates based on N-(phosphinomethyl)iminodiacetic acid: supramolecular layere
Hydrogencyanamido bridged multinuclear copper(II) complexes: from strong antiferromagnetic couplings
Indirect Transformation of Coordination-Polymer Particles into Magnetic Carbon-Coated Mn3O4 (Mn3O4@C
Efficient blue emitters based on 1,3,5-triazine for nondoped organic light emitting diode applicatio
Bi-directional-bi-dimensionality alignment of self-supporting Mn3O4 nanorod and nanotube arrays with
Effect of auxiliary ligands on cobalt(II) coordination polymers with 5-(imidazol-1-ylmethyl)isophtha
Biopolymer-assisted construction and gas-sensing study of uniform solid and hollow ZnSn(OH)(6) spher
In Vitro and in Vivo Fluorescent Imaging of a Monofunctional Chelated Platinum Complex Excitable Usi
Cation-Dependent Magnetic Ordering and Room-Temperature Bistability in Azido-Bridged Perovskite-Type
Novel Cobalt(II) Coordination Polymers Constructed from 3,3 ',4,4 '-Oxydiphthalic Acid and N-Donor L
C-C bond cleavage in acetonitrile by copper(II)-bipyridine complexes and in situ formation of cyano-
Reversible color changes of chiral double salts of D-(+)-camphoric diammonium and transition-metal s
Cobalt-Promoted B-H and C-H Activation: Facile B-C Coupling of Carboranedithiolate and Cyclopentadie
An enantioenriched vanadium phosphonate generated via asymmetric chiral amplification of crystalliza
Temperature-dependent I-V characteristics for the nanocomposite semiconducting films composed of a t
Tuning the Solid-State Luminescence of BODIPY Derivatives with Bulky Arylsilyl Groups: Synthesis and
Metal-Organic Frameworks Constructed from Versatile WS4Cux (x-2) Units: Micropores in Highly Interpe
Synthesis and Properties of Fused-Ring-Expanded Porphyrins that were Core-Modified with Group 16 Het
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