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中文摘要：
设计和合成多个系列的多三氮唑配体和多羧酸配体，对多三氮唑配体进行量子化学计算了解其配体特性；从晶体工程和超分子组装原理出发,采用扩散法、溶剂热、微波加热和离子液体体系等合成方法，系统地利用多三氮唑配体和多羧酸配体组合与过渡金属离子以及羟基，设计组装合成大量磁性功能配位聚合物和以金属羟基簇为单元构筑的磁性配位聚合物；测定其晶体结构，研究其磁性能和羟基的磁传递作用，系统地研究影响配位聚合物结构的各种因素，研究和掌握结构和磁性能的关系，希望能够通过预先设计的结构单元来达到控制合成特定磁性能的功能配合物的目标；探索可调节转变温度的自旋交叉功能配合物和金属羟基簇磁体的控制合成，达到能够调控和优化功能配合物的磁性能，并且希望能够从中筛选出具有优越磁性能的功能配合物材料。
英文摘要：
Functional coordination compounds；Structure；Magnetic properties；Triazole；Carboxylate
结论摘要：
配位聚合物化学不仅具有迷人的结构而且在新颖功能材料如磁性功能材料、光电材料、分子器件、气体储存、气体吸附，分子识别，催化和荧光等新材料开发中显示了广泛的、诱人的应用前景。开展系统的功能配位聚合物的合成、结构性能研究，对无机化学、配位化学和结构化学的学科发展以及开发新材料的研究，具有非常重要的科学意义和潜在的应用价值。 研究工作按照项目计划书设计和合成多个系列的长度、形状和刚柔性程度不同的15个多三氮唑配体和不同种类的15个多羧酸配体。从晶体工程和超分子组装原理出发, 通过多三氮唑配体、多羧酸共配体以及过渡金属离子的合理组合，在设计中更注重对配位聚合物结构的调节以及相关功能配位聚合物的合成，设计组装合成了210多个结构新颖的多维配位聚合物。测定配位聚合物的晶体结构，用元素分析、红外、XRD、差热等对其进行表征。研究了影响配位聚合物结构的各种因素（温度、溶剂、金属/配体比和溶液pH等），进行了配位聚合物的设计和控制合成，比较系统地掌握了配位聚合物的设计和控制合成方法。 通过溶液pH等的控制，采用溶剂热合成法成功合成了9个金属羟基簇为单元构筑的磁性配位聚合物，研究了磁性能，结构和磁性能的关系以及羟基的磁传递作用，获得了比较好的磁性能的功能配合物材料。进行了部分功能配位聚合物材料的荧光性能研究，获得了比较好的潜在的荧光功能配合物材料。根据国家目前面临的越来越严重的环境污染问题，增加进行了部分功能配位聚合物材料的催化降解废水中有害的有机颜料的探索研究工作，获得了性能优良的光催化降解有机颜料的催化剂。 本项目的研究对于无机化学、配位化学、结构化学以及材料学的研究有比较重要的贡献。已经在Cryst. Growth. Des., CrystEngComm, RSC Adv., Polyhedron, Inorg. Chem. Commun., J. Coord. Chem., J. Mol. Struct., Chin. J. Chem.等发表了40篇SCI源期刊论文, 其中影响因子大于4.0论文10篇和最新影响因子3.84论文3篇。
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期刊论文
Three cobalt coordination polymers based on bis(1,2,4-triazol-1-ylmethyl)benzene positional isomer l
Tuning Cobalt Coordination Architectures by Bis(1,2,4-triazol-1-ylmethyl)benzene Position Isomers an
An unusual three-dimensional coordination network formed by parallel polythreading of two-fold polyc
Syntheses, structures and magnetic properties of five iron(II) coordination polymers with flexible b
Syntheses, crystal structures and luminescent properties of three novel manganese coordination polym
Syntheses and Structures of Three Copper Coordination Polymers Based on Bis(triazol-1-ylmethyl)benze
Two Unusual Two-dimensional (4,4) Network Cadmium Coordination Polymers Based on Flexible Bis(triazo
Syntheses, Structures and Properties of Four Manganese Coordination Polymers Derived from 4-Amino-3,
Synthesis, Structure and Luminescent Properties of a Two-dimensional Network Asymmetric Biscarboxyla
Syntheses, structures and luminescence of three cadmium coordination polymers based on 1,2-bis(1,2,4
Syntheses, structures and properties of three cobalt coordination polymers based on flexible bis(tri
Seven structural versatile coordination polymers based on a flexible bis(triazole) and polycarboxyla
Synthesis, Structure, and Properties of a Zinc Coordination Polymer With Flexible Ligand 1,4-Bis(1,2
A polythreading array formed by a (3,5)-connected 3D anionic network and 1D cationic chains: synthes
Construction of Cu？II), Zn？II) and Cd？II) metal– organic frameworks of bis？1,2,4-triazol-4-yl)ethane
Syntheses, structuresand luminescence of a series of coordination polymers constructed with4-substit
Syntheses, structuresand photocatalytic properties of two coordination polymers based onbis(1,2,4-tr
Structurally versatile cadmium coordination polymers based on bis(1,2,4-triazol)ethane and rigid aro
Tuning zinc(II) coordination polymers based on bis(1,2,4-triazol-1-yl) ethane and 5-substituted 1,3-
Four cadmium coordination polymers modulated by bis(triazol-1-yl)propane and inorganic anions: Synth
Syntheses, structures and properties of Mn(II), Zn(II) and Ag(I) coordination polymers with 2-(1,2,4
Syntheses, structuresand luminescence of two cadmium entangled coordination polymers based onbis(imi
Syntheses, structures and properties of two zinc coordination polymers based on bis(triazole) and su
Tuning cadmium coordination architectures using 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene and Sulfois
Syntheses,structures, and properties of two- and threedimensional coordination polymersbased on bis(
Syntheses,structures and properties of eight coordination polymers based onbis(imidazole) and biscar
Two zinc coordination polymers showing five-fold interpenetrated diamondoid network and 2D→3D inclin
Synthesis, Structure and Properties of an Unusual 2D Network Zinc Coordination Polymer Based on Pent
A (3-14)-connected three-dimensional metal-organic framework based on the unprecedented enneanuclear
Three 4-connectednickel coordination polymers affording a 3-D CdSO4 network and two2-D (4,4) network
Two cadmium coordination polymers showing three-fold interpenetrated and self-catenated three-dimens
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