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中文摘要：
本项目针对手性催化剂传统负载方法存在的问题，从手性金属-有机配位聚合物、结构可调手性配体聚合物、功能化离子液体等催化剂体系入手，运用分子组装和组合原理，进一步发展了手性催化剂"自负载"、"离子液功能化的手性有机小分子催化剂"等新策略和新方法，实现了在包括催化不对称氢化、环氧化、环氧开环、Michael 加成、Aldol缩合、芳基化反应、Diels-Alder反应等在内的若干不对称催化反应的高效率、高选择性以及催化剂的简单回收和循环再利用，发现了一些影响负载化手性催化剂选择性、活性、稳定性的因素与规律，在手性催化剂负载化、特别是在手性催化剂自负载、手性离子液仿生催化等方面取得了一些有特色的创新性成果。项目执行四年来，已在重要国际性期刊上发表论文48篇，主编国内和国外专著各一部，在国内、外专著中撰写8个章节，申请专利6项, 获得授权专利6项，项目组主要成员应邀在国际学术会议和双边会议上作大会和邀请报告31次，部分成果获得2008年度上海市自然科学奖一等奖和2009年度国家自然科学奖二等奖。
结论摘要：
英文主题词asymmetric catalysis;chiral catalyst;immobilization;self-supporting;ionic liquid
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
Functionalized Chiral Ionic Liquids: A New Type of Asymmetric Organocatalysts and Nonclassical Chira
Chiral Amine-Polyoxometalate Hybrids as Recoverable Asymmetric Enamine Catalysts under Neat and Aque
Rhodium/diene-catalyzed asymmetric arylation of N-sulfonyl indolylimines: a new access to highly opt
Highly Enantioselective Synthesis of (Diarylmethyl)amines by Rhodium-Catalyzed Arylation of N-Nosyli
Nickel-Catalyzed Asymmetric Ullmann Coupling for the Synthesis of Axially Chiral Tetra-ortho-Substit
Chiral pyrrolidine-azole conjugates: Simple and efficient asymmetric organocatalysts for Michael add
Mechanistic Investigation of Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Reaction of
Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselec
Functionalized Chiral Ionic Liquid Catalyzed Asymmetric S(N)1 alpha-Alkylation of Ketones and Aldehy
Generation of self-supported Noyori-type catalysts using achiral bridged-BIPHEP for heterogeneous as
Spiro[4,4]-1,6-nonadiene-Based Phosphine-Oxazoline Ligands for Iridium-Catalyzed Enantioselective Hy
Self-supported BINOL-Zn catalysts for heterogeneous enantioselective epoxidation of (E)-alpha,beta-u
Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymme
Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applicati
Noncovalently supported heterogeneous chiral amine catalysts for asymmetric direct aldol and Michael
Solution structure and behavior of benzophenone-based achiral bisphosphine ligands in noyori-type Ru
Facile Preparation of alpha-Aryl Nitriles by Direct Cyanation of Alcohols with TMSCN Under the Catal
Insight into the mechanism of the asymmetric ring-opening aminolysis of 4,4-dimethyl-3,5,8-trioxabic
Synergistic effect of binary component ligands in chiral catalyst library engineering for enantiosel
Modular chiral bidentate phosphonites: Design, synthesis, and application in catalytic asymmetric hy
Functionalized chiral ionic liquid catalyzed enantioselective desymmetrizations of prochiral ketones
Chiral amine-polyoxometalate hybrids as highly efficient and recoverable asymmetric enamine catalyst
Surfactant-Type Asymmetric Organocatalyst: Organocatalytic Asymmetric Michael Addition to Nitrostyre
Functionalized chiral ionic liquids as highly efficient asymmetric organocatalysts for Michael addit
会议论文
Highly Efficient Chiral Organometallic Catalysts for Homo- and Heterogeneous Asymmetric Hydrogenatio
Development of Novel Chiral Phosphorus Ligands for Homogeneous and Heterogeneous Enantioselective Ca
New Developments in Asymmetric C-C Bond Formation using N-tert-Butanesulfinyl Imines and Bicyclo[ 3.
Design and Development of New Chiral Diene Ligands with Bicyclo[ 3.3.0 ] Backbone for Asymmetric Cat
Development of Novel Chiral Phosphorous Ligands for Enantioselective Homogeneous and Heterogeneous C
Development of New Synthetic Strategies: Towards the Asymmetric Synthesis of Some Structurally Impor
Development of Homogeneous and Heterogeneous Asymmetric Catalysts for Practical Enantioselective Rea
Highly Efficient Chiral Organometallic Catalysts for Homo- and Heterogeneous Asymmetric Hydrogenatio
Development of Homogeneous and Heterogeneous Chiral Catalysts for Practical Enantioselective Reactio
Probing the Chemistry of N-tert-Butanesulfinyl Imines: New Advances in Asymmetric Synthesis of Chira
Highly Efficient Chiral Organometallic Catalysts for Homo- and Heterogeneous Asymmetric Hydrogenatio
Access to Enantioenriched Homoallylamines by Efficient Asymmetric Nucleophilic Allylation of N-Sulfi
Development of Highly Efficient Chiral Catalysts for Asymmetric Reactions: Practical Synthesis of Ch
Development of Highly Efficient Chiral Catalysts for Asymmetric Reactions: Practical Synthesis of Ch
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