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中文摘要：
在推进剂的催化燃烧中，实现燃烧催化剂高能与钝感的统一是该领域研究的重点，选择高效低污染的催化剂种类符合研究的发展方向。本课题立意于含能燃烧催化剂的高能、钝感及低污染的和谐，从分子结构的设计入手，对高能钝感化合物四唑和三嗪进行化学修饰，继而制备高能钝感金属盐类新型含能燃烧催化剂并进行详细的物理化学及结构表征；基于热化学和热分析手段进行催化剂的能量评价及其与推进剂其他组分的相容性试验，进行金属盐类高能化合物的感度测定，寻求高能与钝感的统一；开展添加单一催化剂和复合催化剂的推进剂全组份的流变学研究，探索催化剂最佳形貌的工艺要求；试验添加单一或复合燃烧催化剂在双基推进剂中的催化燃烧效果，获得燃烧催化剂的催化评价；结合燃烧性能试验，确定非铅盐高能钝感催化剂的基础配方。结果将为双基复合固体推进剂提供高能、钝感、低污染燃烧催化剂品种，对调节推进剂的燃烧性能的及提高推进剂的能量具有重要的实用价值。
结论摘要：
英文主题词energetic coordination compound; high energy with low sensitivity; combustion catalyst; thermodynamics
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