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中文摘要：
本研究拟采用碳纳米角及功能化产物作为组装体，结合静电纺丝技术和自组装策略，研制基于碳基组装体的特定功能化导向的电化学传感器，阐明以碳纳米角为代表的碳基纳米材料的具体结构与其电催化性能的关系。在此基础上，针对含羟基或氨基的食源性污染物，以牺牲空间法为制备策略，通过静电纺丝技术将碳纳米角与分子印迹材料相结合，制备含碳纳米角的分子印迹纳米纤维，从而改善其包括分子识别性能、结合容量等在内的特性。将此类具有分子识别功能的材料装配于电化学界面，结合电化学、电致化学发光等终端检测技术，实现对食源性污染物的高性能检测。探讨包括纺丝聚合物、纺丝控制参数、分子印迹材料制备方法、碳纳米角引入聚合物的策略等因素对该型传感器的影响，建立适合批量制备性能稳定的无机纳米材料/聚合物修饰的电化学仿生传感器的新方法。本项目的开展将有效扩展碳纳米角的应用领域，为基于分子印迹电纺材料的仿生识别传感器的研究提供有益的实践经验。
结论摘要：
英文主题词carbon nanohorn；sensor；electrochemistry；foodborne contaminants；
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期刊论文
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