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中文摘要：
1．总结了金属、配体、结构如何影响配合物的NLO性质，成果即将在2010年美国的Nova Science 出版社出版的著作"Organometallic Compounds: Preparation, Structure and Properties"上发表；运用我们提出的"量子化学解释NLO性质"的方法，对二茂铁羧酸配合物和Ag的氮杂环配合物的NLO作了进一步的研究。2．金属配聚物的中心金属在单晶状态下可以被配位能力更强的金属取代，取代后的产物还能够保持单晶，这些成果在07年的Inorg.Chem.和08年的Chem. Eur. J.等杂志上发表。3．配合物的性质，尤其是催化、生物活性等这些受中心金属离子控制的性质，可以通过配合物中心金属离子的交换进行改变，我们通过配合物中心金属的置换诱导单晶到单晶的转换来调控配合物的结构以期达到调控配合物的性质，该论文发表在08年的JACS上。4.配合物中的骨架阴离子也可以在固态下被取代，通过SEM和AFM对其反应机理进行了研究，结果在09年的Chem. Eur. J.上发表。
结论摘要：
英文主题词Third-order NLO properties; influence factors; central metal exchange; single-crystal to single-crystal transformation; modifying properties
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