欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
位置：立项数据库 > 立项详情页
中文摘要：
催化创新群体在具有挑战性的多相手性催化研究新方向上取得了一批创新成果。例如，在纳米孔内的手性催化环氧化；表面上的手性催化加氢和氢甲酰化；固体酸催化表面的手性D-A和Aldol反应以及手性有机-无机杂化材料合成等方面取得重要进展。在项目执行期间，在国际刊物上发表手性研究论文70余篇，申请专利12件，受邀做大会报告和Keynote报告11次。被邀请在催化领域权威综述刊物Catal. Rev.上发表关于多相手性催化的综述文章；邀请为Chem. Commun.撰写关于纳米孔内手性催化的Feature Article；为纪念均相手性催化国际著名科学家Noyori教授70岁生日被邀在Chem. Asian J.特刊上撰写多相手性催化Focus Review文章。 在项目执行六年中，已有基础研究成果开始向工业应用转化，努力为解决国家重大应用需求贡献力量。另外，本项目还在国内率先研制出手性拉曼光谱仪，并取得技术突破，已成功获得手性分子的手性拉曼光谱。在国际上最早将手性拉曼光谱用于手性催化反应机理研究并取得重要进展。
结论摘要：
英文主题词Chiral synthesis; Nanopores; Chiral surface; Heterogeneous catalysis; Spectroscopy
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
Density functional theory study of CHx (x=1-3) adsorption on clean and CO precovered Rh(111) surface
Enhanced cooperative activation effect in the hydrolytic kinetic resolution of Epoxides on [Co(salen
Adsorption of ethanediamine on colloidal silver: A surface-enhanced raman spectroscopy study combine
Charge transfer between triphenyl phosphine and colloidal silver: A SERS study combined with DFT cal
Pore-size tunable mesoporous zirconium organophosphonates with chiral (L)-proline for enzyme adsorpt
Tandem Ring-Opening/Closing Reactions of N-Ts Aziridines and Aryl Propargyl Alcohols Promoted by t-B
Asymmetric transfer hydrogenation using recoverable ruthenium catalyst immobilized into magnetic mes
The enantioselective cyanosilylation of aldehydes on a chiral VO(Salen) complex encapsulated in SBA-
Chirality inversion in enantioselective hydrogenation of isophorone over Pd/MgO catalysts in the pre
Thieme Chemistry Journal Awardees - Where Are They Now? Bifunctional Silver Acetate Catalyzed Asymme
Epoxidation of allylic alcohols on self-assembled polyoxometalates hosted in layered double hydroxid
Alkali-hydrolysis of D-glucono-delta-lactone studied by chiral Raman and circular dichroism spectros
Highly enantioselective iridium-Catalyzed hydrogenation of 2-Benzylquinolines and 2-Functionalized a
L-Prolinamide functionalized mesoporous silicas: Synthesis and catalytic performance in direct aldol
Structural control of mesoporous ethane-silicas with trans-(1R,2R)-diaminocyclohexane in the pore an
Electronic and steric effects of bis(oxazolinyl)pyridine ligands on asymmetric Diels-Alder reactions
Synthesis of tunable bisphosphine ligands and their application in asymmetric hydrogenation of quino
Asymmetric hydroformylation of olefins catalyzed by rhodium nanoparticles chirally stabilized with (
Direct immobilization of self-assembled polyoxometalate catalyst in layered double hydroxide for het
Transfer hydrogenation of aldehydes on amphiphilic catalyst assembled at the interface of emulsion d
会议论文
Transfer Hydrogenation of Aldehydes and Asymmetric Direct Aldol Reaction on Amphiphilic Catalysts As
Heterogeneous asymmetric hydroformylation of olefins on chirally modified/stabilized rhodium nanocat
Epoxidation of olefins on polyoxometalate nanoclusters selectively assembled in layered double hydro
相关项目
李灿的项目