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中文摘要：
合成一系列杯芳烃衍生物，通过它们与有机锡前体化合物的反应制备出多种类型的有机锡杯芳烃配合物；通过各种手段对配合物进行表征，并通过X射线衍射技术测定它们的结构；总结有机锡杯芳烃配合物的合成及结构方面的规律性。考察这类化合物对酯化反应和酯交换反应的催化性能，为寻找新型有机锡催化剂做出贡献。
结论摘要：
有机锡化合物是分子中含有Sn—C键的一类金属有机化合物。随着人们对有机锡化合物研究的不断深入，有机锡化合物作为一类重要的有机金属化合物已被广泛应用于催化化学、防污涂料和 PVC稳定剂等领域。作为超分子化学的第三代主体分子，杯芳烃比冠醚和环糊精更容易进行化学修饰, 能派生出种类繁多性能各异的杯芳烃衍生物。目前已对杯芳烃金属配合物的合成、结构及热力学稳定性等进行了大量研究工作，取得了丰富的研究成果。有机锡化学和杯芳烃化学是两个十分重要的研究领域，两个领域的研究均取得了丰富的研究成果。以有机锡{[R3Sn]+、[R2Sn]2+ 和[RSn]3+}作为阳离子，以杯芳烃及其种类繁多的衍生物作为配体相结合可以得到一大类有机锡杯芳烃配合物，目前这方面的研究还是空白。通过本项目的研究，合成了一系列杯芳烃衍生物，通过它们与有机锡前体化合物的反应制备了多种类型的有机锡杯芳烃配合物；用各种手段对配合物进行了表征，并通过X射线衍射技术测定了它们的结构。研究发现杯芳烃衍生物配体的结构对它们与有机锡的结合方式有显著的影响。考察了这些杯芳烃有机锡化合物的催化性质，发现它们对酯化反应和酯交换反应有很好的催化性能，为实际应用提供研究基础。
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