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中文摘要：
配位聚合物是利用配位键对有机分子和金属离子在晶体中的有序排列进行控制的结果，运用晶体工程策略设计具有特定结构和性能的配位聚合物是实现从分子到材料的一条重要途径，已成为当前配位化学、超分子化学以及材料化学等领域的主流和热点之一。而具有不同配位功能和结构信息的有机配体（建筑块）的设计、合成和筛选是配位聚合物化学中最重要的主题和根本所在。本项目拟首次将功能化多唑烷类衍生物配体系统地引入到此研究领域，设计并合成三大类各具特色的功能化多唑烷化合物，并以之为桥联建筑块在不同反应条件下与金属离子通过配位驱动组装来构筑各种具有网络结构的配位聚合物。系统深入的研究它们的结构化学、形成过程动力学、热力学以及光、磁、吸附分离和催化等材料性能。结合理论化学工具，研究外因变化对配位聚合物形成过程的影响并总结归纳其形成的一般规律和内在机理等，以期达到定向可控制备新型分子基材料的目的。
结论摘要：
英文主题词Functionalized poly-azolylalkane derivative; Crystal Engineering; Coordination polymer; Molecular design; Structure and function
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