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中文摘要：
将化学工程基本原理与方法应用于纳米材料制备与组装过程，建立了以材料结构为过程控制和优化目标的开发方法；发展了火焰燃烧、静电自组装、介孔限域反应组装等新技术，开发了多种新颖结构金属氧化物、硫化物和聚合物基复合新材料，提出了基于化学工程原理控制材料结构的新思路；创新性地提出了材料结构控制方法及反应器设计原理，实现了纳米材料制备过程的工业化放大。主持了国家自然科学基金重点、973项目前期研究专项及863计划等项目；第一完成人获省部级科技进步一等奖2项、二等奖1项和自然科学奖二等奖2项；申请中国发明专利53项，其中授权17项；在Adv Mater、Cryst Growth Des、Appl Catal B等国内外期刊发表论文270余篇，SCI收录125篇，EI收录173篇，发表论文被国内外他引1600余次。2001年教育部跨世纪优秀人才，2007年上海领军人才,2008年上海青年科技英才。
英文摘要：
Nanomaterials；Structure control；Confined assembly；Process scale-up；Chemical engineering
结论摘要：
近年来，纳米材料的合成取得了突破性进展，从单纯的合成和表征发展到在纳米尺度控制材料形态和结构，以及通过组装等方法形成具有特定结构的复合材料体系。本项目主要开展纳米材料制备、结构调控与化学工程基础研究，目标是在开发新颖结构纳米材料的基础上，发展化学工程学科的基本理论和方法，并推进纳米材料的产业化和应用项目设计了气相火焰燃烧合成的多重射流燃烧反应器，借助于流体混合、火焰温度场和停留时间分布控制制备了一维纳米结构、介孔结构以及半球异质结构等新颖纳米材料，提出反应器设计原理和放大准则。揭示了表面传递/反应与晶面生长之间的匹配关系，首次制备了高指数晶面为主导的锐钛型二氧化钛单晶等纳米材料；阐明了固/液界面传递、反应与材料成核生长间的关系，控制制备了金属氧化物和介孔碳等复合材料，在锂离子电池和超级电容器等方面具有良好的应用前景。创新性地提出了反应与传质解耦并强化传质制备主-客体复合材料的方法，实现了树状大分子封装以及介孔孔道组装贵金属、半导体和石墨烯等量子点等，复合体系兼有客体量子点和主体材料的独特性能。提出了弹性体和无机颗粒协同改性聚合物复合材料的思路，发展了多元复合材料的增韧机理及结构控制方法，开发的聚合物复合材料在全国多家企业实现了推广应用，创造了良好的经济和社会效益。申请中国发明专利32项，授权中国发明专利34项。在JCR I-II区期刊发表SCI收录论文75篇，包括Adv. Mater. 1篇，Angew. Chem. Int. Ed. 1篇，Energy Environ. Sci. 2篇，ACS Nano 1篇、Chem. Commun. 12篇，Nanoscale 6篇，J. Mater. Chem. (A) 9篇和Ind. Eng. Chem. Res. 12篇，其中ESI高引论文15篇，ESI热点论文3篇，已被SCI他引2100余次。项目立项以来，承担人作为第一完成人获得了国家科技进步二等奖、教育部自然科学一等奖和上海市科技进步一等奖；获得上海市自然科学牡丹奖和全国优秀科技工作者，入选国家百千万人才工程并被授予“有突出贡献中青年专家”荣誉称号。研究团队中1人获得国家优秀青年科学基金资助，2人入选教育部新世纪优秀人才，2人入选上海高校“东方学者”特聘教授，1人入选上海市曙光学者，1人入选上海青年科技启明星计划。指导毕业博士研究生8人，硕士研究生10人。
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
One-step preparation, characterization and visible-light photocatalytic activity of Cr-doped TiO2 wi
Interfacial Synthesis and Supercapacitive Performance of Hierarchical Sulfonated Carbon Nanotubes/Po
A green and high energy density asymmetric supercapacitor based on ultrathin MnO2 nanostructures and
Peapod-like nickel@mesoporous carbon core-shell nanowires: a novel electrode material for supercapac
Phase-segregation induced growth of core-shell alpha-Fe2O3/SnO2 heterostructures for lithium-ion bat
Anisotropic photoelectric film assembled from mesoporous silica (MS)@CuO@FeS2 composite microspheres
Preparation of azithromycin microcapsules by a layer-by-layer self-assembly approach and release beh
Gold/mesoporous silica-fiber core-shell hybrid nanostructure: a potential electron transfer mediator
In situ assembly of graphene sheets-supported SnS2 nanoplates into 3D macroporous aerogels for high-
Multifunctional MnO2 nanosheet-modified Fe3O4@SiO2/NaYF4:Yb, Er nanocomposites as novel drug carrier
Non-isothermal crystallization behaviors of PBT nucleated with elastomer-modified nano-SiO2, a comme
The production of flexible and electrically conductive polyethylene-carbon nanotube shish-kebab stru
Construction of core-shell Fe2O3@SnO2 nanohybrids for gas sensors by a simple flame-assisted spray p
Multifunctional Fe3O4@Ag/SiO2/Au Core-Shell Microspheres as a Novel SERS-Activity Label via Long-Ran
Highly compressible magnetic liquid marbles assembled from hydrophobic magnetic chain-like nanoparti
Functional mesoporous carbon nanotubes and their integration in situ with metal nanocrystals for enh
Heteroepitaxial growth of ZnO branches selectively on TiO2 nanorod tips with improved light harvesti
Planar scattering from hierarchical anatase TiO2 nanoplates with variable shells to improve light ha
Synthesis and Structural and Electrical Characteristics of Polypyrrole Nanotube/TiO2 Hybrid Composit
Synthesis and Characterization of Polypyrrole/Graphite Oxide Composite by In Situ Emulsion Polymeriz
Electrical properties and morphology of highly conductive composites based on polypropylene and hybr
Self-Cleaning Films with High Transparency Based on TiO2 Nanoparticles Synthesized via Flame Combust
Highly efficient dye-sensitized solar cells by using a mesostructured anatase TiO2 electrode with hi
Large-scale, uniform, single-crystalline Cd(OH)(2) hexagonal platelets for Cd-based functional appli
In-situ fabrication of CNT/TiO2 interpenetrating network film on nickel substrate by chemical vapour
Controlled synthesis of hierarchical polyaniline nanowires/ordered bimodal mesoporous carbon nanocom
Facile and controllable fabrication of three-dimensionally quasi-ordered macroporous TiO2 for high p
Hydrothermal fabrication of Ni3S2/TiO2 nanotube composite films on Ni anode and application in photo
A Highly Efficient Catalyst toward Oxygen Reduction Reaction in Neutral Media for Microbial Fuel Cel
Preparation and characterization of photocatalytic carbon dots-sensitized electrospun titania nanost
Fabrication of polyaniline/mesoporous carbon/MnO2 ternary nanocomposites and their enhanced electroc
Multifunctional Magnetic Composite Microspheres with in Situ Growth Au Nanoparticles: A Highly Effic
Fabrication and electrochemical characterization of polyaniline nanorods modified with sulfonated ca
Morphological Evolution from SnO2 Quantum Dots to Quantum Chains inside Channels of Mesoporous Spher
Photoelectronic properties of horseradish peroxidase-functionalized CdSe/silica mesoporous composite
Improving photoelectrochemical activity of dye sensitized solar cell by a bilayered electrode with a
The Effects of Copper and Polytetrafluoroethylene (PTFE) on Thermal Conductivity and Tribological Be
Interfacial Confined Formation of Mesoporous Spherical TiO2 Nanostructures with Improved Photoelectr
High-performance supercapacitor material based on Ni(OH)(2) nanowire-MnO2 nanoflakes core-shell nano
One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol an
Hierarchical porous nanostructures assembled from ultrathin MnO2 nanoflakes with enhanced supercapac
Inhibited Transesterification of Poly(Butylene Terephthalate)/Poly(Ethylene Terephthalate)/SiO(2) Na
Hierarchical self-assembly of ultrathin nickel hydroxide nanoflakes for high-performance supercapaci
Electrocatalytic Oxidation of Glucose by the Glucose Oxidase Immobilized in Graphene-Au-Nafion Bioco
A new fabrication method of uniformly distributed TiO2/CNTs composite film by in-situ chemical vapor
Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devic
Higher charge/discharge rates of lithium-ions across engineered TiO2 surfaces leads to enhanced batt
Ultra-thin anatase TiO2 nanosheets dominated with {001} facets: thickness-controlled synthesis, grow
Mixed Solvents Assisted Flame Spray Pyrolysis Synthesis of TiO2 Hierarchically Porous Hollow Spheres
Template-free synthesis of hollow poly(o-anisidine) microspheres and their electrorheological charac
Facile synthesis of upconversion luminescent mesoporous Y2O3:Er microspheres and metal enhancement u
Effect of Perfluoroalkylmethacrylate Ester-grafted-Linear Low-Density Polyethylene on the Tribologic
Enhanced visible light photocatalytic activity of interlayer-isolated triplex Ag@SiO2@TiO2 core-shel
Hierarchical interconnected macro-/mesoporous Co-containing N-doped carbon for efficient oxygen redu
Ultrasound-Triggered Smart Drug Release from Multifunctional Core-Shell Capsules One-Step Fabricated
In situ Au-catalyzed fabrication of branch-type SnO2 nanowires by a continuous gas-phase route for d
会议论文
Dopamine as a carbon source: The selective synthesis of carbon-based hybrids and electrochemical app
Chemical Engineering Fundamental for Fabrication of Functional Nanomaterials-- From Structure Contro
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