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基于可控/“活性”自由基聚合的高分子合成
  • 项目名称：基于可控/“活性”自由基聚合的高分子合成
  • 项目类别：重点项目
  • 批准号：20534010
  • 申请代码：B0401
  • 项目来源：国家自然科学基金
  • 研究期限：2006-01-01-2009-12-31
  • 项目负责人：李子臣
  • 负责人职称：教授
  • 依托单位：北京大学
  • 批准年度：2005
中文摘要：

通过对可逆加成断裂链转移（RAFT）聚合链转移剂的设计合成以及原子转移自由基聚合（ATRP）引发体系和聚合条件的优化实现醋酸乙烯酯、alpha-烯烃等的可控/"活性"自由基聚合和共聚合；发展通过可控/"活性"自由基聚合制备高立构规整性（甲基）丙烯酸酯类聚合物的方法；设计并主要采用RAFT 聚合和ATRP 合成系列新型确定结构、组成、功能的聚合物，如嵌段共聚物和支化聚合物（星形聚合物；聚合物分子刷等）；发展利用可控/"活性"自由基聚合制备新型结构聚合物的新方法，通过对聚合物性质的研究，深入理解聚合物结构的特异性和性能的关系，发现新的功能高分子材料。

中文主题词： 可控/"活性"自由基聚合;高分子合成;嵌段共聚物;支化聚合物;
成果综合统计
成果类型
数量
  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 40
  • 21
  • 0
  • 0
  • 0
期刊论文
Divergent synthesis of dendrimer-like macromolecules through a combination of atom transfer radical
One-pot approach to synthesize star-shaped polystyrenes via RAFT-mediated radical copolymerization
Organic-inorganic hybrid materials by self-gelation of block copolymer assembly and nanoobjects with
Robust organic/inorganic hybrid porous thin films via breath-figure method and gelation process
Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains
Nanoobjects with Controlled Shapes by Self-Assembly of Gelable Block Copolymers
In situ and online monitoring polymerization-induced micellization.
Synthesis of bis(2,2 ': 6 ',2 ''-terpyridine) -terminated telechelic polymers by RAFT polymerization
Double-hydrophilic polymer brushes: Synthesis and application for crystallization modification of ca
Synthesis of well-defined macromonomers by the combination of atom transfer radical polymerization a
Supramolecular hydrogels hybridized with single-walled carbon nanotubes
Formation of CdS nanoparticle necklaces with functionalized dendronized polymers
Preparation of platinum nanoparticles using star-block copolymer with a carboxylic core
Hydrophilic block copolymer aggregation in solution induced by selective threading of cyclodextrins
Gelation inside block copolymer aggregates and organic/inorganic nanohybrids
Dispersing multi-walled carbon nanotubes with water–soluble block copolymers and their use as suppo
Allyl functionalized telechelic linear polymer and star polymer via RAFT polymerization
Synthesis of Well-Defined Azide-Terminated Poly(vinyl alcohol) and Their Subsequent Modification via
Block Copolymers of Poly(ethylene oxide) and Poly(vinyl alcohol) Synthesized by the RAFT Methodology
An all ATRP route to PMMA-PEO-PS and PMAA-PEO-PS miktoarm ABC star terpolymer.
Dual-Responsive Supramolecular Hydrogels from Water-Soluble PEG-Grafted Copolymers and Cyclodextrin.
Cylindrical Molecular Brushes with a Loose Grafting Density.
Intelligent nucleic acid delivery systems based on stimuli-responsive polymers
Codendronized Polymers: Wormlike Molecular Objects with a Segmented Structure
Reactive block copolymer vesicles with an epoxy wall
Onionlike Spherical Polymer Composites with Controlled Dispersion of Gold Nanoclusters
ATRP of 3-(triethoxysilyl)propyl methacrylate and preparation of "stable" gelable block copolymers.
Functionalization of crosslinked vesicles by co-self-assembly of a gelable diblock copolymer and mer
Hierarchical Structure in Oriented Fibers of a Dendronized Polymer.
Acid-Sensitive Polymeric Micelles Based on Thermoresponsive Block Copolymers with Pendent Cyclic Ort
Functional sandwich-like organic/inorganic nanoplates from gelable triblock terpolymers.
Codendronized polymers pendent with alternating dendritic wedges brushes containing metallo-supramol
Synthesis of Well-Defined Poly(vinyl acetate)-b-Polystyrene by Combination of ATRP and RAFT Polymeri
Synthesis, characterization, and self-assembly of comb-dendronized amphiphilic block copolymers.
Preparation of Tadpole-Shaped Amphiphilic Cyclic PS-b-linear PEO via ATRP and Click Chemistry.
会议论文
Codendronized Polymers: Engineering of One Dimensional Molecular Nanoobjects
Dendronized Polymer Brushes－Single Molecular Nano-Objects
反应性嵌段共聚物及其聚集体
Synthesis of Gelable Block Copolymers and Study of Their Properties
Macromolecular Engineering of Poly (vinyl alcohol)
Poly (vinyl alcohol) Containing Block Copolymers: Synthesis and Properties
Functional Block Copolymer Assemblies
New Architectural Polymers by?Controlled Radical Polymerization
New Architectural Polymers By Controlled Radical Polymerization
Tadpole-Shaped Copolymers via ATRP, Click Chemistry and Ring Opening Polymerization
Macromolecular Engineering of Poly (vinyl alcohol)
基于醋酸乙烯酯可控自由基聚合的高分子设计与合成
Synthesis of Tadpole-shaped Copolymers via ATRP and Click Chemistry
原子转移自由基聚合控制聚合物的拓扑结构及支化度
Separation of Cyclic Glycopolymer fom the AB* Inimer Initiated ATRP of a Methacrylate Sugar Monomer
Reactive block copolymers and their vesicles
Shaped Polymer Nano-objects from Gelable Block Copolymers
New Polymer Synthesis by Controlling the Kinetic Process of ATRP
Multiblock Copolymers of Maleic Anhydride and Styrene by Reversible Addition Fragmentation Chain Tra
Controlling the degree of branching in the SCVP of p-(2-bromoisobutyloylmethyl) styrene (VBBiB) by S
Synthesis of Well-defined Poly(vinyl acetate)-b-polystyrene by Combination of ATRP and RAFT Polymeri
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