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中文摘要：
在配位聚合物材料中，由金属有机骨架（MOFs）构筑的多维网络材料基于其结构的多样性和优异的功能特性（储气，催化，光，电，磁等）成为近年来的研究热点。如何根据特定功能和特定结构来设计、组装目标产物，是其中极富挑战性的重要的基础课题。本课题从特定的、只适合目标网络结构所需要的建筑单元块（SBUs）出发，用网络合成的方法，设计合成具有光电磁功能的，各种高对称与非对称网络结构材料。考察诸多因素特别是配体的特殊空间构型，配体的多个配位点与金属离子的配位竞争性，原料组分中阴离子的作用，溶剂等对目标产物结构、性能的影响，系统总结了合成规律，同时研究了目标产物的光学、磁学性质及催化性能，得到了若干有意义的结论 。
结论摘要：
英文主题词coordination polymers; network synthesis;default nets and non-default nets;metal-organic framework.
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期刊论文
Construction of a Hybrid Family Based on Lanthanide-Organic Framework Hosts and Polyoxometalate Gues
Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations (M=Z
Construction of a 3D luminescent cadmium (Ⅱ) network with an unusual deprotonated 1,3-imidazolidine-
Hydrogen-bond networks of 1,3-imidazolidine-2-thione: synthesis and structures of complexes of silve
Controllable synthesis of 1D, 2D and 3D networks: Three novel metal-organic coordination compounds f
Syntheses, structures and properties of novel 3D lanthanide metal-organic frameworks with paddle-whe
Syntheses, crystal structure and luminescence properties of a novel two-dimensional grid framework c
Preparation, structure and properties of 3D supramolecular architecture, on the basis of hydrogen bo
Synthesis and Luminescence Properties of Three High-dimensional Coordination Polymers: Zn(II) with I
Three sandglass-type molybdophosphates obtained via a new route: Synthesis and characterization of X
Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole
Anion-directed assembly of metal-organic coordination complexes from 1,3-imidazolidine-2-thione liga
A Remarkable Member of the Polyoxometalates: The Eight-Nickel-Capped alpha-Keggin Polyoxoazonickelat
Synthesis of 2-D graphite-like and 3-D diamond-like silver(I) polymers with 1,3-imidazolidine-2-thio
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