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中文摘要：
本项目将研究设计和合成一系列的含吡啶的多齿配体，这些配体将含有不同的官能团，如乙酸、硫醇、羧基、羟基、半胱氨酸等，以模拟Hmd氢化酶辅酶配位环境中的部分或全部特征；研究这些配体与Fe(II)在一氧化碳气氛中的反应，合成含有{Fe(II)(cis-CO)2}核的模型化合物，研究这些模型化合物的谱学性质，建立有关谱学性质与铁的氧化态之间的相关关系以确定辅酶中铁的价态；研究含有有关配体及一些小分子无机配体（如氢气、氰酸根、硫氰酸根等）的模型化合物合成及其性质；研究在氢气气氛中有关配体与Fe(II)的反应及所合成的模型化合物的性质。通过本项目的研究，我们希望解决有关这个辅酶的一些配位化学问题，如辅酶中铁的价态的确定；探讨辅酶中的未知配体的可能归属；进一步认识Hmd氢化酶可逆活化分子氢的催化机理。本项目的研究对设计和合成在有机合成催化加氢及氢燃料电池氢气氧化中有应用前景的分子催化材料也有重要意义。
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期刊论文
A novel hexadentate ligand and its complexes with divalent metal ions (Zinc, Copper, and Cobalt): sy
Synthesis and characterisation of anthracene-based fluorophore and its interactions with selected me
A novel ditopic ligand derived from 8?hydroxyquinoline: synthesis, characterization, and its coordin
Synthesis and characterisation of chroman-containing compounds and their preliminary assessment of c
Using pendant ferrocenyl group(s) as an intramolecular standard to probe the reduction of diiron hex
Mechanistic investigations into electrocatalytic substitution reactions of two diiron hexacarbonyl c
Bio-inspired polymer functionalised with a diiron carbonyl model complex and its assembly onto the s
Enable PVC plastic for a novel role: its functionalisation with diiron models of the sub-unit of [Fe
Two Hg(II) complexes with a capped trigonal prismatic geometry derived from multidentate macrocyclic
Synthesis and characterisation of polymeric materials consisting of {Fe2(CO)5}-unit and their releva
Diiron complexes pendant with phenolic group(s) as mimics of the diiron sub-unit of [FeFe]-hydrogena
Two novel oxomolybdenum complexes derived from the reaction of chlorotrisulfido- molybdate precursor
Diiron carbonyl complexes possessing a {Fe(II)Fe(II)} core: synthesis, characterisation, and electro
Influence of the basicity of internal bases in di-iron model complexes on hydrides formation and the
会议论文
Synthesis, characterisation of a complex of Cu(II) with a multidentate macrocyclic ligand and its in
Synthetic Analogues of the Diiron Centre of [FeFe]-hydrogenase and Their Catalysis on Proton Reducti
Synthetic Analogues for the Sub-unit of [FeFe]-hydrogenase and Their Catalysis on Hydrogen Evolution
Mechanistic Investigations into the Proton Reduction Catalysed by Synthetic Analogues Related to the
Synthetic Analogues for the Sub-unit of [FeFe]-hydrogenase and the Mechanistic Investigations of the
Synthetic Analogues of the Diiron Centre of [FeFe]-hydrogenase and Their Catalysis on Proton Reducti
Synthetic Analogues for the Sub-unit of [FeFe]-hydrogenase and Fabrication of Electrocatalytic Elect
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