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中文摘要：
自旋转换和双稳性分子材料在构建分子磁开关、信息存储和显示等自旋电子器件方面应用前景诱人。本项目研究内容包括（1）设计各种拓扑结构的有机铵，通过修饰铵分子上的取代基，改变其拓扑，研究化学环境与其分子拓扑之间的内在联系（2）拟合成一系列有机铵、二硫烯配体及其配合物，把氢键导入过渡金属二硫烯配合物[M(dithiolate)2] (M为三价Ni，Pd or Pt；S = ?)有机铵组装体系（其中铵分子是结构控制单元；过渡金属二硫烯配合物分子是磁电功能性载体），增强体系中协同效应（3）研究配合物的电子、分子和堆积结构，磁电性质和电化学行为等（4）调变铵离子分子性质，控制[M(dithiolate)2]分子组装过程，调节其分子间磁交换性质，诱导自旋转换和双稳性过程，优化材料的功能性（5）理论研究功能性分子[M(dithiolate)2]的自组装规律，及其材料的磁电性质?与其结构之间的相关性。
结论摘要：
英文主题词bis(dithiolato)metal complex; low-dimensional magnet; controlable assembly; spin transition; magnetic bistability
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期刊论文
A radical ion-pair complex exhibiting strong C-H center dot center dot center dot O H-bonding intera
Experimental and theoretical investigations of magnetic properties for two low-dimensional spin syst
Observation of magnetic behavior with two broad maxima of magnetic susceptibility in [Ni(mnt)(2)](-)
One-dimensional (1D) [Ni(mnt)(2)](-)-based spin-Peierls-like complexes: Structural, magnetic and tra
Larger Spontaneous Polarization Ferroelectric Inorganic-Organic Hybrids: [PbI(3)](infinity) Chains D
Ion-pair complexes with strong near infrared absorbance: Syntheses, crystal structures and spectrosc
Observation of metal ion dependent packing structures and magnetic behaviors of metal-bis-1, 2-dithi
A Highly Thermally Stable Ferroelectric Metal-Organic Framework and Its Thin Film with Substrate Sur
Stack Pattern of the Countercation-Modulating Magnetic Property of Low-Dimensional [Pt(mnt)(2)](-) M
Inorganic-organic hybrid compounds based on face-sharing octahedral [PbI(3)](infinity) chains: self-
Unexpected isotopic effect of a deuteriumed countercation on the spin-Peierls-type transitions in qu
Toward design of multiple-property inorganic-organic hybrid compounds based on face-sharing octahedr
Observation of Strongly Antiferromagnetic Exchange Interactions in Four Quasi-One-Dimensional Bis(ma
New europium coordination polymers with efficient energy transfer from conjugated tetracarboxylate l
Two spin systems based on [Ni(dmit)(2)](-) building blocks exhibiting 1-D chain and 2-D sheet struct
Effect of counter cationic geometry on stacking structures and magnetic properties of [Ni(mnt)(2)](-
Observation of steric hindrance effect controlling crystal packing structures and physical propertie
A novel heterostranded double-helical coordination polymer with chiral channels emitting blue fluore
An intriguing NO(2)center dot center dot center dot pi and CN center dot center dot center dot pi in
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